Research Article
Assessment of Heavy Metals Concentration in Arsenic Contaminated Groundwater of the Chaco Plain, Argentina
Table 1
Major ions composition of groundwater from the Comandante Fernández Department, Chaco.
| Sample ID | Depth (m) | pH | EC (mS cm−1) | | Cl− | | | Na+ | K+ | Ca2+ | Mg2+ | Water type |
| M1 | 30 | 7.53 | 2.62 | 656 | 269 | 351 | 23.1 | 644 | 7.10 | 3.54 | 1.65 | Na–HCO3 | M2 | 18 | 7.46 | 0.94 | 509 | 14.4 | 18.0 | 10.4 | 326 | 31.3 | 11.6 | 7.50 | Na–HCO3 | M3 | 13 | 8.08 | 7.07 | 860 | 510 | 3108 | nd | 1595 | 29.8 | 31.9 | 8.30 | Na–SO4 | M4 | 8 | 6.50 | 1.78 | 584 | 99.1 | 335 | 111 | 669 | 110 | 8.96 | 5.03 | Na–SO4 | M5 | 5 | 7.82 | 1.55 | 681 | 99.2 | 209 | 2.50 | 338 | 20.0 | 10.9 | 16.6 | Na–HCO3 | M6 | 20 | 7.11 | 0.83 | 408 | 21.1 | 159 | 12.2 | 132 | 13.9 | 24.5 | 11.4 | Na–HCO3 | M7 | 18 | 6.90 | 1.27 | 490 | 57.1 | 226 | 21.2 | 221 | 11.0 | 9.10 | 5.50 | Na–HCO3 | M8 | 20 | 7.68 | 2.69 | 497 | 427 | 369 | 49.3 | 1034 | 16.5 | 77.4 | 44.3 | Na–Cl | M9 | 13 | 8.25 | 1.34 | 895 | 45.4 | 45.0 | nd | 257 | 2.10 | 7.39 | 5.43 | Na–HCO3 | M10 | 220 | 7.98 | 21.5 | 936 | 8193 | 2070 | 12.2 | 5857 | 32.2 | 206 | 44.7 | Na–Cl | M11 | 50 | 7.89 | 2.44 | 135 | 135 | 480 | nd | 522 | 19.2 | 101 | 47.9 | Na–SO4 | M12 | 15 | 6.96 | 0.95 | 679 | 111 | 165 | 4.35 | 213 | 15.2 | 20.4 | 6.45 | Na–HCO3 | M13 | 12 | 7.29 | 1.36 | 722 | 140 | 107 | 2.10 | 382 | 9.10 | 1.40 | 0.54 | Na–HCO3 | M14 | 12 | 7.93 | 1.49 | 654 | 129 | 83.1 | 14.4 | 806 | 10.0 | 2.30 | 0.52 | Na–HCO3 | M15 | 12 | 7.61 | 2.37 | 769 | 512 | 412 | 107 | 531 | 17.2 | 18.9 | 12.8 | Na–Cl | M16 | 35 | 7.51 | 0.69 | 198 | 89.2 | 136 | 2.30 | 200 | 6.87 | 28.5 | 7.54 | Na–HCO3 | M17 | 15 | 6.84 | 4.48 | 760 | 1447 | 431 | 20.1 | 825 | 23.2 | 14.9 | 46.4 | Na–Cl | M18 | 8 | 6.91 | 3.36 | 448 | 1661 | 182 | 14.5 | 1161 | 12.1 | 122 | 56.9 | Na–Cl | M19 | 12 | 6.78 | 1.75 | 302 | 408 | 335 | 200 | 132 | 12.9 | 6.46 | 2.18 | Na–Cl | M20 | 13 | 7.78 | 4.41 | 751 | 1425 | 421 | 20.3 | 775 | 18.4 | 22.7 | 59.8 | Na–Cl | M21 | 15 | 8.28 | 8.56 | 1017 | 908 | 3485 | 27.3 | 1814 | 19.4 | 63.4 | 78.7 | Na–SO4 | M22 | 17 | 7.36 | 0.88 | 251 | 140 | 49.2 | 24.5 | 216 | 18.4 | 12.5 | 0.92 | Na–Cl | M23 | 10 | 7.24 | 1.59 | 980 | 28.0 | 113 | 13.4 | 309 | 16.3 | 9.37 | 3.50 | Na–HCO3 | M24 | 8 | 7.16 | 1.06 | 806 | 104 | 35.0 | 19.3 | 661 | 19.0 | 32.4 | 20.3 | Na–HCO3 | M25 | 14 | 7.31 | 23.3 | 835 | 5536 | 1486 | 19.5 | 3158 | 22.4 | 109 | 152 | Na–Cl | M26 | 12 | 7.95 | 1.33 | 356 | 112 | 117 | nd | 877 | 21.2 | 71.6 | 32.6 | Na–HCO3 | M27 | 50 | 7.25 | 4.18 | 651 | 571 | 190 | nd | 836 | 23.3 | 50.1 | 22.3 | Na–HCO3 | M28 | 14 | 7.88 | 9.76 | 321 | 1142 | 804 | nd | 1969 | 69.8 | 432 | 147 | Na–Cl | M29 | 15 | 7.06 | 5.35 | 405 | 1099 | 707 | 45.2 | 1065 | 57.7 | 319 | 120 | Na–Cl | M30 | 10 | 7.64 | 1.41 | 864 | 110 | 164 | 12.2 | 320 | 15.2 | 33.2 | 22.1 | Na–HCO3 | M31 | 50 | 7.76 | 3.05 | 964 | 244 | 519 | 6.50 | 563 | 7.59 | 4.57 | 2.24 | Na–HCO3 | M32 | 12 | 7.29 | 8.05 | 1868 | 1300 | 43.2 | 10.1 | 489 | 3.12 | 355 | 92.2 | Na–HCO3 | M33 | 10 | 7.26 | 5.29 | 679 | 762 | 582 | 2.30 | 747 | 19.5 | 123 | 88.4 | Na–Cl | M34 | 12 | 7.53 | 1.15 | 500 | 85.1 | 91.2 | 21.3 | 268 | 9.71 | 19.1 | 11.3 | Na–HCO3 | M35 | 8 | 8.17 | 2.98 | 1652 | 165 | 116 | 25.4 | 549 | 6.16 | 3.74 | 3.90 | Na–HCO3 | M36 | 10 | 7.17 | 11.8 | 1868 | 742 | 1506 | 2.25 | 2100 | 2.71 | 90.4 | 150 | Na–SO4 | M37 | 8 | 7.55 | 1.74 | 920 | 73.2 | 108 | 13.5 | 823 | 8.54 | 15.6 | 9.30 | Na–HCO3 | M38 | 20 | 8.94 | 6.33 | 214 | 1012 | 1350 | nd | 994 | 10.8 | 18.3 | 55.8 | Na–Cl | M39 | 15 | 7.26 | 10.0 | 463 | 2634 | 1258 | 72.1 | 1029 | 67.8 | 498 | 202 | Na–Cl | M40 | 52 | 7.00 | 19.4 | 764 | 4636 | 1520 | 23.4 | 200 | 54.2 | 183 | 182 | Mg–Cl | M41 | 65 | 8.51 | 24.9 | 817 | 5121 | 1537 | 39.4 | 2100 | 67.9 | 67.0 | 144 | Na–Cl | M42 | 12 | 8.92 | 1.43 | 668 | 26.0 | 35.5 | 21.2 | 244 | 11.5 | 8.06 | 3.37 | Na–HCO3 | M43 | 8 | 7.28 | 1.81 | 618 | 234 | 74.2 | 4.50 | 765 | 32.4 | 57.6 | 16.3 | Na–HCO3 | M44 | 11 | 7.07 | 2.50 | 723 | 450 | 90.1 | 56.1 | 223 | 30.3 | 132 | 64.6 | Ca–Cl | M45 | 12 | 6.81 | 14.4 | 298 | 5674 | 26.3 | 42.4 | 459 | 28.6 | 1100 | 400 | Ca–Cl |
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Nd: non detected. All concentrations are expressed as mg L−1.
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