Table of Contents
ISRN Environmental Chemistry
Volume 2013 (2013), Article ID 930573, 8 pages
http://dx.doi.org/10.1155/2013/930573
Research Article

Gas Chromatography Mass Spectrometry Identification of Labile Radicals Formed during Pyrolysis of Catechool, Hydroquinone, and Phenol through Neutral Pyrolysis Product Mass Analysis

1Laboratory of Applied Ecology, Faculty of Agronomic Sciences, University of Abomey-Calavi, 03 BP 3908 Cotonou, Benin
2Laboratoire de Science et Technique de l’Eau, Ecole Polytechnique d’Abomey-Calavi, Universite d’Abomey-Calavi, 04 BP 0823 Cotonou, Benin
3Laboratoire d’Hydrologie Appliquee, Universite d’Abomey-Calavi, BP 526 Abomey-Calavi, Benin

Received 7 October 2013; Accepted 28 November 2013

Academic Editors: M. Millet and Q. Zhou

Copyright © 2013 Julien Adounkpe et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Catechol, hydroquinone, and phenol are known to be environmental pollutants due to their ability to generate environmentally free radicals, which cause millions of deaths worldwide. Recently, efforts have been done to precisely identify the origin and the nature of those free radicals employing EPR-LTMI technique. All the three precursors generate cyclopentadienyl radical as major pyrolysis products and phenoxyl radical as both pyrolysis and photolysis products which were obtained from phenol; ortho-semiquinone and para-semiquinone were seen, respectively, from the pyrolysis of catechol and hydroquinone. However, it has been suspected that the solely use of the EPR-LTMI did not allow the isolation of the more labile radicals that is supposedly terminated by radical-radical or radical-surface interaction. The present study reports the gas chromatography mass analysis of the pyrolysis products from catechol, hydroquinone, and phenol. Naphthalene , indene, and hydroxyindene were observed as the pyrolysis products of hydroquinone, while fluorene, 1H-indenol and its isomer 1H-inden-1-one 2,3 dihydro, acenaphthylene, benzofuran-7-methyl, and benzofuran-2-methyl were observed as pyrolysis products of catechol. Dibenzo dioxin and dibenzo furan were observed from pyrolysis of catechol and hydroquinone. Those products result from the combination of radicals such as cyclopentadienyl, para-semiquinone, ortho-semiquinone, hydroxyl-cyclohexadienyl, phenoxyl, and most importantly Hydroxycyclopentadienyl which was not identified by EPR-LTMI.