Table of Contents
ISRN Nanotechnology
Volume 2014, Article ID 634679, 8 pages
http://dx.doi.org/10.1155/2014/634679
Research Article

Heterogeneous Catalysis of C–O Bond Cleavage for Cellulose Deconstruction: A Potential Pathway for Ethanol Production

1Department of Chemistry, Tuskegee University, Tuskegee, AL 36088, USA
2Center for Advanced Materials, Tuskegee University, Tuskegee, AL 36088, USA

Received 26 September 2013; Accepted 5 December 2013; Published 20 February 2014

Academic Editors: C. Li, R. Redón, and Y.-S. Shon

Copyright © 2014 Kristy Crews et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. C. Davis, “Transportation Energy Data Book 18,” Tech. Rep. ORNL-6941, Oak Ridge National Laboratory, Oak Ridge, Tenn, USA, September1998, http://cta.ornl.gov/data/index.shtml. View at Google Scholar
  2. U.S. Consumer Energy Report, February 2012, http://www.energytrendsinsider.com/research/crude-oil/where-the-us-gets-its-oil-from/.
  3. D. Mohan, C. U. Pittman Jr., and P. H. Steele, “Pyrolysis of wood/biomass for bio-oil: a critical review,” Energy & Fuels, vol. 20, no. 3, pp. 848–889, 2006. View at Publisher · View at Google Scholar
  4. “Technical, Environmental and Economic Feasibility of Bio-oil in New-Hampshire's North Country,” UNH Bio-oil Team Report (Final Report submitted to NH IRC), August 2002www.unh.edu/p2/biooil/bounhif.pdf.
  5. V. Balan et al., “Process for producing sugars and ethanol using corn stillage,” US Patent, 2009.
  6. M. Darapuneni, B. A. Stewart, D. B. Parker, C. A. Robinson, A. J. Megel, and R. E. DeOtte Jr., “Agronomic evaluation of ashes produced from combusting beef cattle manure for an energy source at an ethanol production facility,” Applied Engineering in Agriculture, vol. 25, no. 6, pp. 895–904, 2009. View at Google Scholar · View at Scopus
  7. USDA Agricultural Baseline Projections to 2015, Paul Westcott, ERS Contact, OCE-2006-1, USDA, Office of the Chief Economist, World Agricultural Outlook Board, February 2006.
  8. “Fuel Ethanol: Background and Public Policy Issues,” CRS Report for Congress 2006.
  9. A. Demirbas, “Bioethanol from cellulosic materials: a renewable motor fuel from biomass,” Energy Sources, vol. 27, no. 4, pp. 327–337, 2005. View at Publisher · View at Google Scholar
  10. J.-C. Frigon and S. R. Guiot, “Biomethane production from starch and lignocellulosic crops: A comparative review,” Biofuels, Bioproducts and Biorefining, vol. 4, no. 4, pp. 447–458, 2010. View at Publisher · View at Google Scholar · View at Scopus
  11. L. S. E. Putri, Nasrulloh, and A. Haris, “Bioethanol production from sweet potato using combination of acid and enzymatic hydrolysis,” in Proceedings of the 2nd International Conference on Mechanical and Aerospace Engineering (ICMAE '11), pp. 1767–1772, Trans Tech Publications, Bangkok, Thailand, July 2011.
  12. L. Bai, H. Wan, and S. C. Street, “Preparation of ultrafine FePt nanoparticles by chemical reduction in PAMAM-OH template,” Colloids and Surfaces A, vol. 349, no. 1–3, pp. 23–28, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. K. Esumi, A. Suzuki, A. Yamahira, and K. Torigoe, “Role of poly (amidoamine) dendrimers for preparing nanoparticles of gold, platinum, and silver,” Langmuir, vol. 16, no. 6, pp. 2604–2608, 2000. View at Google Scholar · View at Scopus
  14. F. Zeng and S. C. Zimmerman, “Dendrimers in supramolecular chemistry: From molecular recognition to self-assembly,” Chemical Reviews, vol. 97, no. 5, pp. 1681–1712, 1997. View at Google Scholar · View at Scopus
  15. H. Ye, R. W. J. Scott, and R. M. Crooks, “Synthesis, characterization, and surface immobilization of platinum and palladium nanoparticles encapsulated within amine-terminated poly(amidoamine) dendrimers,” Langmuir, vol. 20, no. 7, pp. 2915–2920, 2004. View at Publisher · View at Google Scholar · View at Scopus
  16. A. Fukuoka and P. L. Dhepe, “Catalytic conversion of cellulose into sugar alcohols,” Angewandte Chemie International Edition, vol. 45, no. 31, pp. 5161–5163, 2006. View at Publisher · View at Google Scholar · View at Scopus
  17. V. B. Agbor, N. Cicek, R. Sparling, A. Berlin, and D. B. Levin, “Biomass pretreatment: Fundamentals toward application,” Biotechnology Advances, vol. 29, no. 6, pp. 675–685, 2011. View at Publisher · View at Google Scholar · View at Scopus
  18. J. Zakzeski, P. C. A. Bruijnincx, A. L. Jongerius, and B. M. Weckhuysen, “The catalytic valorization of lignin for the production of renewable chemicals,” Chemical Reviews, vol. 110, no. 6, pp. 3552–3599, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. J. M. Nichols, L. M. Bishop, R. G. Bergman, and J. A. Ellman, “Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers,” Journal of the American Chemical Society, vol. 132, no. 36, pp. 12554–12555, 2010. View at Publisher · View at Google Scholar · View at Scopus