Table of Contents
ISRN Inorganic Chemistry
Volume 2014, Article ID 709258, 4 pages
Research Article

Unusual Seven Coordination of Oxovanadium(V) Oximato Complex: Synthesis and X-Ray Crystal Structure

Chemistry Department, Faculty of Science, Damietta University, New Damietta 34517, Egypt

Received 3 November 2013; Accepted 1 December 2013; Published 4 March 2014

Academic Editors: K. Y. Choi, R. Meijboom, and S. Turmanova

Copyright © 2014 Shadia A. Elsayed et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. H. Michibata, Vanadium and Molecular Biological Approaches, Springer, Amsterdam, The Netherlands, 2012.
  2. V. Sharma, V. Sharma, R. Bohra, J. E. Drake, M. B. Hursthouse, and M. E. Light, “Synthesis and characterization of some oxovanadium(V) complexes with internally functionalized oximes: crystal and molecular structures of heptacoordinated [VO{ON=C(CH3)(C4H3O−2)}3] and [VO{=C(CH3)(C4H3S−2)}3] · 0.5C6H6,” Inorganica Chimica Acta, vol. 360, no. 6, pp. 2009–2015, 2007. View at Publisher · View at Google Scholar · View at Scopus
  3. A. M. El-Hendawy, A. M. Fayed, and M. R. Mostafa, “Complexes of a diacetylmonoxime Schiff base of S-methyldithiocarbazate (H2damsm) with Fe(III), Ru(III)/Ru(II), and V(IV); Catalytic activity and X-ray crystal structure of [Fe(Hdamsm)2]NO2·H2O,” Transition Metal Chemistry, vol. 36, no. 4, pp. 351–361, 2011. View at Publisher · View at Google Scholar · View at Scopus
  4. N. M. H. Salem, L. El-Sayed, and M. F. Iskander, “Metal complexes derived from hydrazoneoxime ligands: IV. Molecular and supramolecular structures of some nickel(II) complexes derived from diacetylmonoxime S-benzyldithiocarbazonate,” Polyhedron, vol. 27, no. 15, pp. 3215–3226, 2008. View at Publisher · View at Google Scholar · View at Scopus
  5. W. A. Wolkert and T. J. Hoffman, “Therapeutic radiopharmaceuticals,” Chemical Reviews, vol. 99, pp. 2269–2292, 1999. View at Google Scholar
  6. H. Schmidt, M. Bashirpoor, and D. Rehder, “Structural characterization of possible intermediates in vanadium-catalysed sulfide oxidation,” Journal of the Chemical Society, no. 19, pp. 3865–3870, 1996. View at Google Scholar · View at Scopus
  7. R. A. Rowe and M. M. Jones, “Preparation from vanadium(V) oxide through prior reduction to oxovanadium(IV) ion,” Inorganic Synthesis, vol. 5, p. 114, 1957. View at Google Scholar
  8. A. Altomare, G. Cascarano, C. Giacovazzo et al., “SIR92: a program for automatic solution of crystal structures by direct methods,” Journal of Applied Crystallography, vol. 27, p. 435, 1994. View at Google Scholar
  9. S. Mackay, C. Gilmore, C. J. Edwards, N. S. tewart, and K. Shankland, MasXus Computer Program for the Solution and Refinement of Crystal Structures Bruker Nonius, 1999.
  10. Z. Otwinowski and W. Minor, “Processing of X-ray diffraction data collected in oscillation mode,” in Methods in Enzymology, C. W. Carter Jr. and R. M. S. weet, Eds., vol. 276, p. 307, Academic Press, New York, NY, USA, 1997. View at Google Scholar
  11. R. Neumann and I. Assael, “Vanadium(V)/vanadium(III) redox couple in acidic organic media. Structure of a vanadium(III)-tetraethylene glycol pentagonal-bipyramidal complex ([V(teg)(Br)2]+Br-),” Journal of the American Chemical Society, vol. 111, no. 22, pp. 8410–8413, 1989. View at Google Scholar · View at Scopus
  12. K.-Y. Choi, S.-M. Yang, K.-C. Lee et al., “Synthesis, properties, and crystal structures of mononuclear nickel(II) and copper(II) complexes with 2-oximino-3-thiosemicarbazone-2,3-butanedione,” Transition Metal Chemistry, vol. 33, no. 1, pp. 99–105, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. E. W. Yemeli Tido, G. O. R. Alberda van Ekenstein, A. Meetsma, and P. J. van Koningsbruggen, “Study of neutral Fe(III) complexes of pyridoxal-N-substituted thiosemicarbazone with desolvation-induced spin-state transformation above room temperature,” Inorganic Chemistry, vol. 47, no. 1, pp. 143–153, 2008. View at Publisher · View at Google Scholar · View at Scopus
  14. J. Tatiersky, P. Schwendt, M. Sivák, and J. Marek, “Racemic monoperoxovanadium(v) complexes with achiral OO and on donor set heteroligands: synthesis, crystal structure and stereochemistry of [NH3(CH2)2NH3][VO(O2)(ox)(pic)]·2H2O and [NH3(CH2)2NH3][VO(O2)(ox)(pca)],” Dalton Transactions, no. 13, pp. 2305–2311, 2005. View at Publisher · View at Google Scholar · View at Scopus
  15. G. Desiraju and T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology, Oxford University Press, Oxford, UK, 1999.
  16. R. Vargas, J. Garza, D. A. Dixon, and B. P. Hay, “How strong is the Cα–HOC hydrogen bond?” Journal of the American Chemical Society, vol. 122, pp. 4750–4755, 2000. View at Google Scholar