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Journal of Applied Chemistry
Volume 2014 (2014), Article ID 529764, 5 pages
Research Article

Synthesis of Triphenyltin (IV) and Dibutyltin (IV) Complexes of 1-Aryl-2,5-dithiohydrazodicarbonamides and Their Characterization

Department of Chemistry, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005, India

Received 28 October 2013; Accepted 3 February 2014; Published 5 March 2014

Academic Editor: Guennadi E. Zaikov

Copyright © 2014 Rashmi B. Rastogi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Organotin complexes of the types Ph3SnL and Bu2SnL [where Ph = phenyl and Bu = butyl; HL = 1-phenyl-2,5-dithiohydrazodicarbonamide (HPhthc), 1-benzyl-2,5-dithiohydrazodicarbonamide (Hbzthc), 1-(4-ethoxyphenyl)-2,5-dithiohydrazodicarbonamide (HEtOPhthc)] have been prepared. Molar conductance studies demonstrate the nonionic behavior of the complexes. The 1H and 13C nuclear magnetic resonance and FAB mass spectra of the complexes are consistent with the proposed stoichiometry. Infrared spectra suggest an anionic bidentate coordinating behavior of the ligands.