Table of Contents
Journal of Applied Chemistry
Volume 2016, Article ID 3757418, 10 pages
http://dx.doi.org/10.1155/2016/3757418
Research Article

A Novel Tris(2-aminoethyl)amine Based Tripodal Ligand: Synthesis and Solution Coordination Studies with Trivalent Iron and Chromium

1Department of Chemistry, National Institute of Technology, Kurukshetra, Haryana 136119, India
2Department of Chemistry, Sant Longowal Institute of Engineering and Technology, Longowal, Punjab 148106, India

Received 31 July 2016; Accepted 19 October 2016

Academic Editor: Khalid Z. Elwakeel

Copyright © 2016 Minati Baral et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A novel tris(2-aminoethyl)amine (TREN) based tripodal ligand TRENOL (L) has been synthesized and characterized by elemental analysis and UV-VIS, IR, 1H, and 13C NMR spectroscopic methods. The coordination behaviour of the ligand with H+ and trivalent metal ions, Fe(III) and Cr(III), was investigated in aqueous medium at 0.1 M KCl at °C by potentiometric and spectrophotometric studies. Tripodal ligand showed seven protonation constants in the adopted pH range 2–11 and its electronic spectra exhibited three bands at 216, 323, and 423 nm. Ligand formed various metal complex species of the type MLH5, MLH4, MLH3, MLH, and ML with trivalent metal ions. The determined values of the formation constants (for ML species) of the ligand with Fe(III) and Cr(III) were 24.19 and 18.64, respectively. Molecular modeling studies revealed that the metal complexes formed distorted octahedral geometry. Besides, ligand showed fluorescence at 496 nm when excited at 289 nm. The fluorescence behaviour of the ligand in the presence of Fe(III) ions showed noticeable quenching in comparison to the other metal ions at physiological pH (7.4). So, as per the outcomes of the present study, TRENOL has the potential to be used as the iron detector in environmental, agricultural, and medical fields.