Journal of Analytical Methods in Chemistry

Review Article

Surfactant Modified/Mediated Thin-Layer Chromatographic Systems for the Analysis of Amino Acids

Table 3

value of amino acids on different surfactant modified surfaces: data is extracted from references [6–8].


Amino acids	values with chromatographic systems

L-Histidine	= 0.93 (S₈, M₄₄), = 0.92 (S₁₇, M₄₄), = 0.88 (S₂₀, M₄₄), = 0.97 (S₈, M₄₅), = 0.94 (S₁₇, M₄₅), = 0.89 (S₂₀, M₄₅), = 0.95 (S₈, M₄₆), = 0.90 (S₁₇, M₄₆), = 0.88 (S₂₀, M₄₆), = 0.67 (S₃, M₄₇), = 0.68 (S₄, M₄₇), = 0.62 (S₅, M₄₇), = 0.60 (S₆, M₄₇), = 0.67 (S₇, M₄₇), = 0.64 (S₉, M₄₇), = 0.72 (S₁₀, M₄₇), = 0.65 (S₁₃, M₄₇), = 0.71 (S₁₄, M₄₇), = 0.63 (S₁₈, M₄₇), = 0.66 (S₁₉, M₄₇), = 0.94 (S₁₁, M₄₈), = 0.96 (S₁₂, M₄₈), = 0.95 (S₁₅, M₄₈), = 0.95 (S₁₆, M₄₈), = 0.55 (S₂₁, M₄₈), = 0.56 (S₂₂, M₄₈), = 0.63 (S₂₃, M₄₈), = 0.66 (S₂₄, M₄₈)

DL-Phenylalanine	= 0.68 (S₃, M₄₇), = 0.82 (S₄, M₄₇), = 0.82 (S₅, M₄₇), = 0.82 (S₆, M₄₇), = 0.76 (S₇, M₄₇), = 0.64 (S₉, M₄₇), = 0.75 (S₁₀, M₄₇), = 0.74 (S₁₃, M₄₇), = 0.80 (S₁₄, M₄₇), = 0.84 (S₁₈, M₄₇), = 0.85 (S₁₉, M₄₇)

L-Phenylalanine	= 0.77 (S₈, M₄₄), = 0.80 (S₁₇, M₄₄), = 0.74 (S₂₀, M₄₄), = 0.96 (S₈, M₄₅), = 0.85 (S₁₇, M₄₅), = 0.78 (S₂₀, M₄₅), = 0.82 (S₈, M₄₆), = 0.82 (S₁₇, M₄₆), = 0.75 (S₂₀, M₄₆), = 0.76 (S₁₁, M₄₈), = 0.77 (S₁₂, M₄₈), = 0.72 (S₁₅, M₄₈), = 0.78 (S₁₆, M₄₈), = 0.53 (S₂₁, M₄₈), = 0.69 (S₂₂, M₄₈), = 0.56 (S₂₃, M₄₈), = 0.61 (S₂₄, M₄₈)

DL-Tryptophan	= 0.80 (T) (S₃, M₄₇), = 0.90 (S₄, M₄₇), = 0.90 (S₅, M₄₇), = 0.90 (S₆, M₄₇), = 0.89 (S₇, M₄₇), = 0.75 (S₉, M₄₇), = 0.87 (S₁₀, M₄₇), = 0.71 (S₁₃, M₄₇), = 0.88 (S₁₄, M₄₇), = 0.89 (S₁₈, M₄₇), = 0.89 (S₁₉, M₄₇)

L-Tryptophan	= 0.86 (S₁₁, M₄₈), = 0.87 (S₁₂, M₄₈), = 0.88 (S₁₅, M₄₈), = 0.90 (S₁₆, M₄₈), = 0.54 (S₂₁, M₄₈), = 0.65 (S₂₂, M₄₈), = 0.38 (S₂₃, M₄₈), = 0.57 (S₂₄, M₄₈)

DL-Methionine	= 0.78 (T) (S₃, M₄₇), = 0.86 (S₄, M₄₇), = 0.86 (S₅, M₄₇), = 0.86 (S₆, M₄₇), = 0.91 (S₇, M₄₇), = 0.83 (S₉, M₄₇), = 0.79 (S₁₀, M₄₇), = 0.78 (S₁₃, M₄₇), = 0.81 (S₁₄, M₄₇), = 0.84 (S₁₈, M₄₇), = 0.85 (S₁₉, M₄₇)

L-Lysine	= 0.92 (S₈, M₄₄), = 0.91 (S₁₇, M₄₄), = 0.96 (S₂₀, M₄₄), = 0.96 (S₈, M₄₅), = 0.94 (S₁₇, M₄₅), = 0.95 (S₂₀, M₄₅), = 0.96 (S₈, M₄₆), = 0.92 (S₁₇, M₄₆), = 0.95 (S₂₀, M₄₆), = 0.60 (S₃, M₄₇), = 0.77 (S₄, M₄₇), = 0.56 (S₅, M₄₇), = 0.55 (S₆, M₄₇), = 0.67 (S₇, M₄₇), = 0.63 (S₉, M₄₇), = 0.71 (S₁₀, M₄₇), = 0.58 (S₁₃, M₄₇), = 0.69 (S₁₄, M₄₇), = 0.59 (S₁₈, M₄₇), = 0.60 (S₁₉, M₄₇), = 0.95 (S₁₁, M₄₈), = 0.89 (S₁₂, M₄₈), = 0.70 (S₁₅, M₄₈), = 0.84 (S₁₆, M₄₈), = 0.64 (S₂₁, M₄₈), = 0.63 (S₂₂, M₄₈), = 0.65 (S₂₃, M₄₈), = 0.66 (S₂₄, M₄₈)

DL-Threonine	= 0.90 (S₃, M₄₇), = 0.92 (S₄, M₄₇), = 0.86 (S₅, M₄₇), = 0.86 (S₆, M₄₇), = 0.97 (S₇, M₄₇), = 0.81 (S₉, M₄₇), = 0.94 (S₁₀, M₄₇), = 0.86 (S₁₃, M₄₇), = 0.94 (S₁₄, M₄₇), = 0.90 (S₁₈, M₄₇), = 0.88 (S₁₉, M₄₇)

L-Threonine	= 0.89 (S₁₁, M₄₈), = 0.93 (S₁₂, M₄₈), = 0.88 (S₁₅, M₄₈), = 0.91 (S₁₆, M₄₈), = 0.30 (S₂₁, M₄₈), = 0.35 (S₂₂, M₄₈), = 0.34 (S₂₃, M₄₈), = 0.38 (S₂₄, M₄₈)

L-Leucine	= 0.84 (S₈, M₄₄), = 0.82 (S₁₇, M₄₄), = 0.79 (S₂₀, M₄₄), = 0.82 (S₈, M₄₅), = 0.80 (S₁₇, M₄₅), = 0.74 (S₂₀, M₄₅), = 0.83 (S₈, M₄₆), = 0.84 (S₁₇, M₄₆), = 0.81 (S₂₀, M₄₆), = 0.80 (S₃, M₄₇), = 0.77 (S₄, M₄₇), = 0.84 (S₅, M₄₇), = 0.83 (S₆, M₄₇), = 0.85 (S₇, M₄₇), = 0.80 (S₉, M₄₇), = 0.87 (S₁₀, M₄₇), = 0.75 (S₁₃, M₄₇), = 0.85 (S₁₄, M₄₇), = 0.79 (S₁₈, M₄₇), = 0.85 (S₁₉, M₄₇), = 0.71 (S₁₁, M₄₈), = 0.75 (S₁₂, M₄₈), = 0.70 (S₁₅, M₄₈), = 0.76 (S₁₆, M₄₈), = 0.69 (S₂₁, M₄₈), = 0.64 (S₂₂, M₄₈), = 0.63 (S₂₃, M₄₈), = 0.72 (S₂₄, M₄₈)

D-Leucine	= 0.84 (T) (S₃, M₄₇), = 0.84 (S₄, M₄₇), = 0.81 (S₅, M₄₇), = 0.81 (S₆, M₄₇), = 0.83 (S₇, M₄₇), = 0.81 (S₉, M₄₇), = 0.84 (S₁₀, M₄₇), = 0.76 (S₁₃, M₄₇), = 0.83 (S₁₄, M₄₇), = 0.79 (S₁₈, M₄₇), = 0.83 (S₁₉, M₄₇)

DL-Isoleucine	= 0.79 (T) (S₃, M₄₇), = 0.79 (S₄, M₄₇), = 0.78 (S₅, M₄₇), = 0.78 (S₆, M₄₇), = 0.87 (S₇, M₄₇), = 0.79 (S₉, M₄₇), = 0.79 (S₁₀, M₄₇), = 0.73 (S₁₃, M₄₇), = 0.80 (S₁₄, M₄₇), = 0.68T (S₁₈, M₄₇), = 0.80 (S₁₉, M₄₇)

L-Isoleucine	= 0.67 (S₁₁, M₄₈), = 0.70 (S₁₂, M₄₈), = 0.72 (S₁₅, M₄₈), = 0.69 (S₁₆, M₄₈), = 0.74 (S₂₁, M₄₈), = 0.76 (S₂₂, M₄₈), = 0.76 (S₂₃, M₄₈), = 0.77 (S₂₄, M₄₈),

L-Norleucine	= 0.77 (S₈, M₄₄), = 0.71 (S₁₇, M₄₄), = 0.77 (S₂₀, M₄₄), = 0.80 (S₈, M₄₅), = 0.75 (S₁₇, M₄₅), = 0.81 (S₂₀, M₄₅), = 0.77 (S₈, M₄₆), = 0.77 (S₁₇, M₄₆), = 0.79 (S₂₀, M₄₆), = 0.73 (S₁₁, M₄₈), = 0.75 (S₁₂, M₄₈), = 0.73 (S₁₅, M₄₈), = 0.73 (S₁₆, M₄₈), = 0.71 (S₂₁, M₄₈), = 0.76 (S₂₂, M₄₈), = 0.74 (S₂₃, M₄₈), = 0.76 (S₂₄, M₄₈)

DL-Valine	= 0.76 (S₃, M₄₇), = 0.90 (S₄, M₄₇), = 0.75 (S₅, M₄₇), = 0.74 (S₆, M₄₇), = 0.85 (S₇, M₄₇), = 0.89 (S₉, M₄₇), = 0.85 (S₁₀, M₄₇), = 0.78 (S₁₃, M₄₇), = 0.84 (S₁₄, M₄₇), = 0.83 (S₁₈, M₄₇), = 0.83 (S₁₉, M₄₇)

L-Valine	= 0.82 (S₁₁, M₄₈), = 0.80 (S₁₂, M₄₈), = 0.85 (S₁₅, M₄₈), = 0.80 (S₁₆, M₄₈), = 0.75 (S₂₁, M₄₈), = 0.66 (S₂₂, M₄₈), = 0.62 (S₂₃, M₄₈), = 0.79 (S₂₄, M₄₈)

L-Proline	= 0.84 (S₈, M₄₄), = 0.77 (S₁₇, M₄₄), = 0.80 (S₂₀, M₄₄), = 0.75 (S₈, M₄₅), = 0.76 (S₁₇, M₄₅), = 0.81 (S₂₀, M₄₅), = 0.76 (S₈, M₄₆), = 0.74 (S₁₇, M₄₆), = 0.77 (S₂₀, M₄₆), = 0.72 (S₁₁, M₄₈), = 0.77 (S₁₂, M₄₈), = 0.73 (S₁₅, M₄₈), = 0.75 (S₁₆, M₄₈), = 0.75 (S₂₁, M₄₈), = 0.70 (S₂₂, M₄₈), = 0.69 (S₂₃, M₄₈), = 0.66 (S₂₄, M₄₈)

Glutamic acid	= 0.95 (S₈, M₄₄), = 0.96 (S₁₇, M₄₄), = 0.95 (S₂₀, M₄₄), = 0.95 (S₈, M₄₅), = 0.96 (S₁₇, M₄₅), = 0.94 (S₂₀, M₄₅), = 0.92 (S₈, M₄₆), = 0.95 (S₁₇, M₄₆), = 0.96 (S₂₀, M₄₆), = 0.93 (S₁₁, M₄₈), = 0.97 (S₁₂, M₄₈), = 0.88 (S₁₅, M₄₈), = 0.94 (S₁₆, M₄₈), = 0.25 (S₂₁, M₄₈), = 0.24 (S₂₂, M₄₈), = 0.30 (S₂₃, M₄₈), = 0.17 (S₂₄, M₄₈)

L-Serine	= 0.91 (S₈, M₄₄), = 0.93 (S₁₇, M₄₄), = 0.97 (S₂₀, M₄₄), = 0.95 (S₈, M₄₅), = 0.92 (S₁₇, M₄₅), = 0.95 (S₂₀, M₄₅), = 0.96 (S₈, M₄₆), = 0.96 (S₁₇, M₄₆), = 0.95 (S₂₀, M₄₆), = 0.94 (S₁₁, M₄₈), = 0.97 (S₁₂, M₄₈), = 0.91 (S₁₅, M₄₈), = 0.96 (S₁₆, M₄₈), = 0.40 (S₂₁, M₄₈), = 0.38 (S₂₂, M₄₈), = 0.41 (S₂₃, M₄₈), = 0.49 (S₂₄, M₄₈)

L-Alanine	= 0.90 (S₈, M₄₄), = 0.96 (S₁₇, M₄₄), = 0.95 (S₂₀, M₄₄), = 0.96 (S₈, M₄₅), = 0.94 (S₁₇, M₄₅), = 0.95 (S₂₀, M₄₅), = 0.96 (S₈, M₄₆), = 0.96 (S₁₇, M₄₆), = 0.90 (S₂₀, M₄₆), = 0.97 (S₁₁, M₄₈), = 0.94 (S₁₂, M₄₈), = 0.95 (S₁₅, M₄₈), = 0.91 (S₁₆, M₄₈), = 0.61 (S₂₁, M₄₈), = 0.65 (S₂₂, M₄₈), = 0.62 (S₂₃, M₄₈), = 0.56 (S₂₄, M₄₈)

L-Tyrosine	= 0.94 (S₈, M₄₄), = 0.94 (S₁₇, M₄₄), = 0.96 (S₂₀, M₄₄), = 0.87 (S₈, M₄₅), = 0.94 (S₁₇, M₄₅), = 0.93 (S₂₀, M₄₅), = 0.97 (S₈, M₄₆), = 0.95 (S₁₇, M₄₆), = 0.94 (S₂₀, M₄₆), = 0.94 (S₁₁, M₄₈), = 0.92 (S₁₂, M₄₈), = 0.93 (S₁₅, M₄₈), = 0.94 (S₁₆, M₄₈), = 0.60 (S₂₁, M₄₈), = 0.69 (S₂₂, M₄₈), = 0.49 (S₂₃, M₄₈), = 0.57 (S₂₄, M₄₈)

L-Arginine	= 0.95 (S₁₁, M₄₈), = 0.89 (S₁₂, M₄₈), = 0.95 (S₁₅, M₄₈), = 0.92 (S₁₆, M₄₈), = N.D (S₂₁, M₄₈), = N.D (S₂₂, M₄₈), = 0.64 (S₂₃, M₄₈), = 0.56 (S₂₄, M₄₈)