Table 2: Validation results of the developed method.

CompoundsLOQMRLCCαCCβ% recovery% RSD% recovery% RSD% recovery % RSD% RSDrRelative uncertainty %Matrix effect
(µg/kg)(µg/kg)(µg/kg)(µg/kg)10 (µg/kg)10 (µg/kg) 25 (µg/kg)25 (µg/kg)50 (µg/kg)50 (µg/kg)

2,4-D (negative)0.997111021331128906108513320.81
2,4,5-T0.998910182685181021793911230.92
2,4-Dimethylaniline0.99881018267911110897811 350.99
Acetamiprid 0.99710101826979102896711330.92
Acrinathrin 0.9981110182610610888104711350.81
Alachlor 0.997111020301081186492313280.81
Amitraz0.997910203086876476314280.81
Atrazine0.9971110172310969459139300.85
Azoxystrobin0.9981110213311491025110414300.92
Bentazon 0.9981210172311859449448280.85
Bifenazate 0.99811102030109101027111611330.92
Bitertanol 0.9981110172311259839738260.88
Boscalid 0.998121015201156110610157300.99
Bromacil 0.9989102030911610814911113420.97
Bromuconazole 0.997111020301099100895614300.90
Bromoxynil 0.99710101723991410699969330.96
Bupirimate 0.9971210203011651005104312260.90
Buprofezin 0.99791017239016901288810260.81
Butocarboxim sulfoxide0.997111017231079118810277331.06
Cadusafos 0.99711101520110119489556300.85
Carbaryl0.99711101723105109458949280.85
Carbendazim 0.9971210203011851225113411301.10
Carbofuran 0.9981210172311649049238260.81
Carbosulfan 0.99791021339110106693615320.96
Carboxin 0.99811101826113690489512280.81
Clofentezine 0.99891017238813981093810260.88
Chloridazon 0.9981010182610211114997711301.03
Chlorfenvinphos 0.998111018261128965100310300.86
Chlorfluazuron 0.99811102133107101145108614301.03
Chloroxuron 0.99711101826108131025104510360.92
Chlorpyrifos 0.997111017231089102610767320.92
Chlorsulfuron 0.99710102133961092588515300.83
Chlorthiamid 0.9979102133921710413114913320.94
Cinidon-ethyl 0.997111017231057100611058320.90
Cyazofamid 0.99711101826112794793410280.85
Cyclanilide0.9971210213311551045113513300.94
Cycloate 0.998111017231061296118859280.86
Cymoxanil 0.998111017231097112610368321.01
Cyproconazole 0.99810101826961092698412280.83
Cyprodinil 0.99891020309116989110911300.88
Demeton-S-methyl 0.9981010203096169811101411280.88
Demeton-S-methylsulfoxide 0.998101013171008101799611350.91
Desmedipham 0.998101013179989888771400.88
Diallate 0.998101020301001312012110614261.08
Diazinon 0.99810101213959926100512320.83
Dichlofluanid 0.9981010172310391048100812260.94
Dichlorprop 0.9989101826885884953800.82
Dichlorvos 0.99891015209314118111091116351.06
Difenoconazole 0.99891015209212100994411280.90
Dimethenamid (sum) 0.9981110172311213989871010280.94
Dimethoate 0.998111017231138104710069260.94
Dimethomorph 0.99891013179112104897514280.94
Dimoxystrobin 0.998101015201018116597512301.05
Diniconazole 0.998101013179719961587910360.86
Dinobuton 0.998101017231041078692611320.82
Dinocap (sum) 0.99812101317115796590414300.86
Dinoterb 0.99712101826115710049849280.90
Diphenylamine 0.999121013171157108590414300.97
Disulfoton-sulfoxide 0.997111013171091086694513300.82
Dithianon0.997111013171066108510236260.97
Diuron 0.999111020301099947101310260.85
Epoxiconazole 0.99711101213105898493411280.88
EPTC0.997111018261137112496410281.01
Ethiofencarb 0.9971210182611579659639260.86
Ethion 0.9981010152010210100898812220.90
Ethirimol 0.998101015209815969111813330.86
Ethofumesate 0.99811101723105119610100713280.86
Etoxazole 0.998111017231148945101411280.85
Ethoxyquin 0.9981010131710013961198411300.86
Famoxadone 0.99811101520112121145117512321.03
Fenamidone 0.99811101317108984891610260.82
Fenamiphos 0.998111017231075106410935320.96
Fenarimol 0.998101013171011199995811230.89
Fenazaquin 0.9971110182611381287113810281.15
Fenbuconazole0.9979101317861694129748320.85
Fenhexamid 0.99711101826114780684513280.82
Fenitrothion 0.997101017239912981194911240.88
Fenoxycarb 0.997910131785161001410389350.90
Fenpropathrin 0.9971010182610012100109997250.90
Fenthion 0.99710102336951211211108712331.01
Flazasulfuron 0.9981010304995101188116715301.06
Fludioxonil 0.998121023361157885100513250.82
Fluazifop-P-butyl 0.998121028461188102696511320.92
Flufenacet 0.9981010254010310969100713280.86
Flufenoxuron 0.998101026439581008105411320.90
Flurochloridone 0.9981010182610010102911267280.92
Flurtamone 0.99810102030103690489410320.81
Flusilazole 0.99810102336104892699611320.83
Flutolanil 0.998121018261156114799710261.03
Foramsulfuron 0.99811102540105486399414260.82
Fosthiazate 0.9978102030821394594313300.85
Furathiocarb0.99712102133115596590512330.86
Heptenophos 0.997101031539915941290711280.85
Hexythiazox 0.99710102540103610049859320.90
Imazalil 0.9971010284695121001188109280.90
Imazamox 0.99781018268411100992612260.90
Imazaquin 0.9971110315311299058631200.81
Imazosulfuron 0.997101025409812951196811360.86
Imidacloprid 0.999910304987121029109615260.92
Indoxacarb 0.999101023369915100693816300.90
Ioxynil 0.999101020309948448158300.81
Iprovalicarb 0.9991010203097121108104715320.99
Isazofos 0.999121021331157945891113260.85
Isoproturon 0.99912102030115890697611380.81
Isoxaben 0.99711102643112511039658300.99
Lufenuron 0.9971010264399498494413300.88
Malathion 0.999121023361157104589613330.94
MCPA0.99791025409391025103711280.92
Mecarbam 0.99811103153105161061494711300.96
MCPP0.998101028461031284997912410.82
Metalaxyl-M 0.998101023369771224101516261.10
Mepanipyrim 0.997101031531021692131071116330.83
Mesosulfuron-methyl 0.99781028468215104593612350.94
Metazachlor 0.997111023361135100593612160.90
S-Metolachlor0.999910182693892797711270.83
Metosulam 0.99911103049110994888814320.85
Metribuzin 0.999111021331051172991615260.82
Monocrotophos 0.997121025401154100388314320.90
Monolinuron 0.9971010284610417921490813280.83
Monuron 0.997111031531148102494513350.92
Omethoate 0.99711102846105994991813390.85
Oxadiargyl 0.997111023361051511011901114300.99
Oxadiazon 0.99710103049968112511256321.01
Oxadixyl 0.997111021331091290108868350.81
Oxamyl 0.9971010304910314961289811330.86
Oxasulfuron 0.99711103356108886887712280.82
Oxycarboxin 0.997121028461157112497612281.01
Oxyfluorfen 0.99791030499281017103611280.91
Penconazole 0.99711102336112710249649280.92
Pendimethalin 0.997111020301138108510846280.97
Pethoxamid 0.99711102846108976481514320.83
Phosalone 0.998101023369611112411258361.01
Phenmedipham 0.998101036629514921388611300.83
Phenthoate0.99712102336115794589612280.85
Phosmet 0.9971010213310011941092913330.85
Phosphamidon 0.99710102133998108795710300.97
Picloram 0.997111021331051296891712360.86
Picolinafen 0.99710102540100121149104912251.03
Pirimicarb 0.99712102336119894297310300.85
Pirimiphos-methyl 0.997121023361157108594512300.97
Prochloraz 0.999121021331155112594518301.01
Profenofos 0.99912102133115710459658300.94
Prometryn 0.9991110213310979459969360.85
Propamocarb 0.99810102540100131021089911300.92
Propanil 0.999121030491157102599612280.92
Propargite 0.99910102643102141121011348301.01
Propham 0.9991010213310213100696510280.90
Propiconazole 0.999101030499861224111614301.10
Propyzamide 0.999810284684109699559330.86
Pymetrozine 0.997101023361011096890711280.86
Pyraclostrobin 0.9971210213311571305119415261.17
Pyridaben 0.99791020308916801281411360.82
Pyridaphenthion 0.9971010233699111209991013261.08
Pyridate 0.9981010315398510649838320.96
Pyriproxyfen 0.997101021331011194686513220.85
Quinalphos 0.99710102336101576690514230.82
Quinoxyfen 0.9991010304999598110028230.88
Quizalofop-P-ethyl0.99712103049115782585514260.84
Rimsulfuron 0.998910264388131043100214260.94
Simazine 0.997111023361061696899311230.86
Spiroxamine 0.9998102133831484982214320.82
Sulfosulfuron 0.997810213382121106111619300.99
Tebuconazole 0.9991010284699109469959250.85
TEPP 0.99791023369071077105611290.96
Terbutryn 0.997121026431158965102311280.86
Terbuthylazine0.9971010203010412118511646261.06
Tetrachlorvinphos 0.997111021331131178890414280.90
Thiabendazole 0.99712102133118698496513300.88
Thiacloprid 0.997111018261061384128958350.82
Thiamethoxam 0.997101033561041911811113811321.06
Thifensulfuron-methyl 0.9979102030911698892915300.88
Thiodicarb 0.99712103153115710259769350.92
Thiophanate-methyl0.997111020301149112695513321.01
Triadimefon 0.99710102846104710669858320.96
Triadimenol 0.997111025401071410669279260.96
Triallate 0.9981110233610691143111412301.03
Triasulfuron 0.99811102030111876591614300.82
Triazophos 0.9981210304911579658759300.86
Tribenuron-methyl 0.998101035599991038101511300.93
Tributylphosphate 0.997101017231041488128958350.81
Trichlorfon 0.9981010254098101043100214270.94
Tridemorph 0.9971010213398179013100511300.81
Trifloxystrobin 0.9971210254011571245114514301.12
Triflumizole 0.99711102030113149259958280.83
Triticonazole 0.9981010172310011106109877320.96
Vamidothion 0.997910213393131186102716281.06
Zoxamide 0.99712102336116772485315250.82
Ciprofloxacin0.99771001241487425611697139380.81
Clindamycin0.9971110121411023106151091012340.96
Chlortetracycline0.9991010010811610179379969140.84
Danofloxacin0.999103040481041487128889240.82
Difloxacin0.9999101113878100796610150.90
Doxycycline hydrate0.9991010011011910414931196810230.84
Flumequine0.9989505458881210511931011220.95
Josamycin0.998910111388121041197912220.94
Lomefloxacin0.999101012139913891199810220.80
Orbifloxacin0.99991011129314107894711200.96
Oxolinic acid0.999111012151101210210102615200.92
Oxytetracycline0.99911100111122114151041295610230.94
Rifampicin0.997101011139898589859150.81
Sarafloxacin0.9971010121410110978102511160.87
Sulfachloropyridazine0.997910011613288131061280910240.96
Sulfaquinoxaline0.99810100111122971599107899240.89
Sulfadiazine0.9978100108116851298998510180.88
Sulfamerazine0.9998100111122851210487579190.94
Sulfathiazole0.9999100113126851110910811017210.98
Sulfamethazine0.999810011412984131049104811210.94
Sulfadoxine0.99991001141298816951295610240.86
Sulfapyridine0.997810011913883111081096810200.97
Sulfaclozine0.9981010011112299109289859160.83
Sulfamethoxazole0.9981010011613210299578759150.86
Tilmicosin0.9991050566298121049105410180.94
Tetracycline0.99910100119138100188489659230.82