Review Article

Magnetic Solid Phase Extraction as a Promising Technique for Fast Separation of Metallic Nanoparticles and Their Ionic Species: A Review of Recent Advances

Table 1

Magnetic adsorbents used for the separation and preconcentration of Ag ions and AgNPs.

AnalyteAdsorbentDetection method (mL)m (mg)LOD (μg/L)RSD (%)Rec. (%)Q m (mg/g)Ref.

Ag(I)AC/γ-Fe2O3-BPDMETAAS25252.303.597–10332.6[53]
Ag(I)TREN-Fe3O4ETAAS100100.80NR96–10297.3[54]
Ag(I)Fe3O4@SiO2@SiC3H6NH2FAAS150101.102.798–10152.3[55]
Ag(I)MBT/SDS-ACMNPsFAAS101000.563.196–10211.6[56]
Ag(I)mGO@SiO2@PPy-PThFAAS50190.102.796–10349.0[57]
Ag(I)Mag-GO@MBT/SDSICP-OES50500.0453.189–92NR[58]
Ag(I)AMT-TMSPT-MNPsICP-OES200500.125.394–10310.4[59]
Ag(I)Fe3O4@PThICP-OES100600.204.289–108NR[60]
Ag(I)DPTH-MNPsICP-OES50500.0305.690–1089.10[61]
Ag(I)DPTH@MGOICP-OES50500.503.293–1069.72[62]
Ag(I)PVIM-MNPsETAAS5057.506.480–11461.4[51]
AgNPsPVIM-MNPsETAAS5058.207.092–12253.2[51]
AgNPsPVPMCMsICP-MS20100.0234.285–93NR[63]
AgNPsCitrateMCMsICP-MS20100.0163.488–97NR[63]
AgNPsPVAMCMsICP-MS20100.0213.788–99NR[63]
Ag2SNPsIOMPsICP-MS50200.0683.070–100NR[64]

ng/L; : sample volume; m: amount of adsorbent; LOD: limit of detection; RSD: relative standard deviation; Rec.: recovery; Qm: adsorption capacity; Ref.: reference; NR: not reported.