Table of Contents
Journal of Catalysts
Volume 2013 (2013), Article ID 586364, 9 pages
http://dx.doi.org/10.1155/2013/586364
Research Article

Synthesis of Catalysts and Its Application for Low-Temperature CO Oxidation

Department of Chemical and Materials Engineering, National Central University, Chung-Li 320, Taiwan

Received 10 January 2013; Revised 21 January 2013; Accepted 31 January 2013

Academic Editor: Adel A. Ismail

Copyright © 2013 Der-Shing Lee and Yu-Wen Chen. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A series of Au/ -TiO2 with various Co/Ti ratios prepared. /TiO2 was prepared by incipient wetness impregnation with aqueous solution of cobalt nitrate. Au catalysts were prepared by deposition-precipitation (DP) method at pH 7 and 338 K. The catalysts were characterized by inductively coupled plasma-mass spectrometry, temperature programming reduction, X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. The reaction was carried out in a fixed bed reactor with a feed containing 1% CO in air at weight hourly space velocities of 120,000 mL/h g and 180,000 mL/h g. High gold dispersion and narrow particle size distribution were obtained by DP method. The addition of into Au/TiO2 enhanced the activity of CO oxidation significantly. Au/5%   -TiO2 had the highest catalyst among all the catalysts. was mainly in the form of nanosize Co3O4 which could stabilize the Au nanoparticles. donated partial electrons to Au. The interactions among Au, , and TiO2 account for the high catalytic activity for CO oxidation.