Table of Contents
Journal of Catalysts
Volume 2014 (2014), Article ID 712067, 6 pages
http://dx.doi.org/10.1155/2014/712067
Research Article

Heterogeneous Fenton-Like Catalytic Removal of Methylene Blue Dye in Water Using Magnetic Nanocomposite (MCM-41/Magnetite)

Department of Chemistry, Federal University of Lavras, P.O. Box 3037, 37200-000 Lavras, MG, Brazil

Received 4 November 2013; Revised 20 February 2014; Accepted 23 February 2014; Published 31 March 2014

Academic Editor: David W. Mazyck

Copyright © 2014 André E. Nogueira et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

In this work, MCM-41, magnetite (MAG), and a composite of magnetite and MCM-41 (MCM-MAG) were synthesized by a simple route for the production of active systems in the decomposition of organic waste. The materials were characterized by N2 adsorption/desorption, X-ray diffraction analysis (XRD), temperature programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). Our results indicated that the decolorization kinetics of the dyes were in the order of MCM-MAG > MCM-41 > magnetite. Mineralization of the dyes was monitored by total organic carbon (TOC) decrease. The dye solutions could be completely decolorized and effectively mineralized, with an average overall TOC removal 43% for a Fenton-like reaction time of 180 min. The degradation activity of the MCM-MAG was stable during four consecutive experiments, confirming their stability and reusability of the composite. The great advantage of this composite is that it may be easily magnetically recovered and reused.