Journal of Chemistry

Journal of Chemistry / 2007 / Article

Open Access

Volume 4 |Article ID 354540 | https://doi.org/10.1155/2007/354540

B. L. Hiran, S. S. Dulawat, Renu Rathore, Neeru Rathore, "Kinetics of Oxidation of Glutathione by Micelle Trapped Tris(benzhydroxamato)iron(III)", Journal of Chemistry, vol. 4, Article ID 354540, 5 pages, 2007. https://doi.org/10.1155/2007/354540

Kinetics of Oxidation of Glutathione by Micelle Trapped Tris(benzhydroxamato)iron(III)

Received31 Jul 2006
Revised13 Oct 2006
Accepted01 Nov 2006

Abstract

Kinetics of the oxidation of glutathione (GSH) by micelle Sodium dodecyl sulphate (SDS) trapped tris(benzhydroxamato)iron(III) (TBH) at pH 3.3 and at 298 K has been described. The reaction is first order in TBS and GSH. Increase in pH decreased the rate. Order in H+ is one The reaction between TBH and GSH on micellar surface (Stern layer) differs from that occurring in bulk aqueous phase in absence of micelle (SDS). Reactive FeL3 species on micellar surface is FeL2+.

Copyright © 2007 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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