Journal of Chemistry

Journal of Chemistry / 2008 / Article

Open Access

Volume 5 |Article ID 348037 | https://doi.org/10.1155/2008/348037

E. Yildiz, N. Bozok, "Synthesis of Compounds Containing Fluorine, Vinylsulfone Groups and Transition Metal Complexes and their Applications to Textiles", Journal of Chemistry, vol. 5, Article ID 348037, 11 pages, 2008. https://doi.org/10.1155/2008/348037

Synthesis of Compounds Containing Fluorine, Vinylsulfone Groups and Transition Metal Complexes and their Applications to Textiles

Received24 Dec 2007
Revised10 Mar 2008
Accepted05 May 2008

Abstract

A ligand which has reactive dye character and its transition metal complexes such as Cu(II), Co(II), Cr(III), Ni(II) containing vinylsulfone and fluorine groups were synthesized. The diazotation reaction has been studied at 0-5°C carefully. Completion of the reaction was monitored by the TLC method. FT-IR, UV, 1H-NMR, TGA and microanalysis methods were used for determination of the synthesized compounds. We assumed that copper complex indicated dimeric structure based on magnetic susceptibility result. All the synthesized compounds which have dye character were applied on cotton, polyamide and nylon fibers. Their dyeing and fastness properties were investigated according to international standards. These properties gave good results for all synthesized dyes except light fastnesses of chromium and nickel complex dyes.

Copyright © 2008 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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