Journal of Chemistry

Journal of Chemistry / 2009 / Article

Open Access

Volume 6 |Article ID 598726 | 4 pages | https://doi.org/10.1155/2009/598726

Photodecomposition of Molybdenum andTungsten Carbonyl Complexes

Received28 Mar 2009
Accepted20 May 2009

Abstract

The photodecomposition of four different colored organometallic molybdenum and tungsten carbonyl complexes, i.e. [Mo(CO)5)2LA] (complex I), [(Mo(CO)3(bipy))2LB] (complex II), [(W(CO)3(tmen))2LB] (complex III) and [Mo(CO)2LC]2 (complex I V) where LA 2-phenyl-1,3-indandione)bis(2-methyl anilines, LB 2-phenyl-1,3-indandione) bis (4-hydroxy anilines and LCbis (2-hydroxo-benzalydine) benzidine ion have been performed at 365 nm in chloroform at 25 °C under oxygen atmosphere. The absorbance spectrum of these complexes has been recorded with the time of irradiation in order to examine the kinetics of photodecomposition. The rate of the photodecomposition process was investigated and the relative values of the rate constants of dissociation (Kd) for the first-order reaction are tabulated. The apparent rate constant of photodecomposition was found to be (8.33-11.50) × 10-5 s-1.

Copyright © 2009 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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