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E-Journal of Chemistry
Volume 7 (2010), Issue 3, Pages 1108-1115
http://dx.doi.org/10.1155/2010/147819

Selective Extraction and Bulk Liquid Membrane Transport of Cu(II) from Aqueous Nitrate Solution in the Presence of Zn(II), Ni(II) and Mn(II) Cations Using Benzoyl Acetone

A. Nezhadali, H. Vahedi, M. Roigar, and A. Sadeghi

Department of Chemistry, Payame Noor University (PNU), Mashhad, Iran

Received 16 November 2009; Accepted 10 January 2010

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The competitive metal ion extraction and transport of Cu(II), Ni(II), Zn(II) and Mn(II) with benzoyl acetone and EDTA was studied. In the experiments the ligand was dissolved in chloroform and the pH and time of extraction or transport were varied. Also the rate of shaking and ligand concentration on the efficiency of extraction and transport was studied. The results revealed that the ligands exclusively extract Cu(II) from the mixture of the above cations.