Journal of Chemistry

Journal of Chemistry / 2010 / Article

Open Access

Volume 7 |Article ID 378561 | 8 pages | https://doi.org/10.1155/2010/378561

Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands

Received10 Apr 2010
Accepted22 May 2010

Abstract

Oxocyanotungsten(IV) complexes, (Ph3P)2 NH2 [WO(CN)3 L–L]. 3H2O and Cs[WO(CN)3L–L].H2O (where L–L = morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), piperidinobenzyl urea (PBU), piperidinobenzyl thiourea (PBTU), morpholinobenzyl urea (MBU) and morpholinobenzyl thiourea (MBTU)) were synthesized. The complexes have been prepared by the reaction of K3Na [WO2(CN)4].6H2O with morpholinobenzyl urea and related ligands in aqueous solution around pH of 7-8. These have been isolated as bis(triphenylphosphine)iminium or cesium salts. The complexes have been characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra, magnetic susceptibility, conductivity measurements and TGA/DTA studies.

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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