Journal of Chemistry

Journal of Chemistry / 2010 / Article

Open Access

Volume 7 |Article ID 594743 | 7 pages | https://doi.org/10.1155/2010/594743

Corrosion Inhibition and Adsorption Characteristics of Tarivid on Mild Steel in H2SO4

Received09 Oct 2009
Accepted05 Dec 2009

Abstract

The corrosion inhibition and adsorption characteristics of (+/-)-9-fluoro-2,3-dihydro-3-methyl-10-(4-methyl-1-piperazinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acid (Tarivid) on the corrosion of mild steel has been studied using thermometric and gasometric methods. The study reveals that tarivid inhibits the corrosion of mild steel in H2SO4. The values of inhibition efficiency of tarivid were found to increase as its concentration increased but decreased with increase in temperature. Activation energies of the inhibited corrosion of mild steel ranged from 39.05 to 50.61 kJ/mol. Values of enthalpy change and free energy of adsorption were negative which indicated exothermic and spontaneous adsorption process. Physical adsorption mechanism is proposed from the obtained kinetic and thermodynamic parameters. Langmuir adsorption isotherm model is obeyed from the fit of the experimental data.

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

292 Views | 1368 Downloads | 3 Citations
 PDF  Download Citation  Citation
 Order printed copiesOrder