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E-Journal of Chemistry
Volume 8, S1, Pages S409-S419

Preparation and Properties of Non-Crosslinked and Ionically Crosslinked Chitosan/Agar Blended Hydrogel Films

Mohamed Mahmoud Nasef,1 Esam A. El-Hefian,2 Sariah Saalah,1 and Adul Hamid Yahaya2

1Chemical Engineering Department, Faculty of Chemical and Natural Resources Engineering, Universiti Teknologi Malaysia, UTM Skudai-81310, Johor, Malaysia
2Chemistry Department, Faculty of Science, University of the Western Mountain, Azzawiyah, Libya

Received 15 February 2011; Accepted 14 April 2011

Copyright © 2011 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Hydrogel films of chitosan (Cs) and agar blends of various proportions were prepared using physical solution blending. Some of the obtained films were ionically cross-linked by treatment with calcium chloride solution. The obtained films were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetry analysis (TGA), differential scanning calorimetery (DSC) and universal mechanical tester. The non-crosslinked Cs/agar blended films showed lower water swelling, melting temperature, stiffer and less elastic properties than that of pure Cs films and higher than pure agar films. Crosslinked blended films displayed further reduction in the swelling and melting temperature while maintained more hydrogel stability.