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E-Journal of Chemistry
Volume 8, Issue 3, Pages 1038-1043
http://dx.doi.org/10.1155/2011/645628

Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater

M. R. Lutfor and M. Y. Mashitah

Faculty of Industrials Sciences and Technology, University Malaysia Pahang, 26300 Gambang, Kuantan, Pahang, Malaysia

Received 6 September 2010; Accepted 22 November 2010

Copyright © 2011 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Synthesis of poly(hydroxamic acid)-poly(amidoxime) chelating ligands were carried out from poly(methyl acrylate-co-acrylonitrile) grafted sago starch and hydroxylamine in alkaline medium. The binding property of metal ions was performed and maximum sorption capacity of the copper was 3.20 mmol/ g and the rate of exchange of some metals was faster, i.e. t½ ≈ 7 min (average). Two types of wastewater containing chromium, zinc, nickel, copper and iron, etc. were used and the heavy metal recovery was found to be highly efficient, about 99% of the metals could be removed from the metal plating wastewater.