Epoxidation of Alkenes with Molecular Oxygen Catalyzed by Immobilized Co(acac)2 and Co(bpy)2Cl2 Complexes within Nanoreactors of Al-MCM-41

Farzaneh, F.; Jalalian, M.; Tayebi, L.

doi:https://doi.org/10.1155/2012/896327

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Volume 9 | Article ID 896327 | https://doi.org/10.1155/2012/896327

Epoxidation of Alkenes with Molecular Oxygen Catalyzed by Immobilized Co(acac)₂ and Co(bpy)₂Cl₂ Complexes within Nanoreactors of Al-MCM-41

F. Farzaneh,¹M. Jalalian,¹and L. Tayebi¹

Received24 Oct 2011

Accepted30 Dec 2011

Abstract

Cobalt complexes with different ligands such as bipyridine, and acetylacetonate were immobilized within nanoreactors of Al-MCM-41, designated as Co(acac)₂/Al-MCM-41 and Co(bipy)₂²⁺/Al-MCM41. The immobilized complexes were characterized by XRD, N₂-adsorption desorption, FT-IR and UV-Vis techniques. It was found that Co(bipy)₂²⁺/Al-MCM41 and Co(acac)₂/Al-MCM-41 successfully catalyze the oxidation of norbornene, styrene, cis-stilbene, trans-stilbene, and cyclohexene with 68% to 100% conversion and 41% to 90% selectivity toward the corresponding epoxides. No desorption was observed during the course of reactions.

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Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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