Aqueous Polymerization of Acrylonitrile with Cerium(IV)- p-Hydroxyacetophenone Redox System

Abstract

Aqueous polymerization of acrylonitrile initiated by Ce(IV)/ p-hydroxy acetophenone (Ce(IV) – HAP) was studied in aqueous solution of sulfuric acid at 40 ^°C. The rate of polymerization was investigated at various concentrations of monomer, initiator, activator, sulfuric acid and the effect of temperature of 30-70 ^°C range was studied. The rate of polymerization is governed by the expression Rp = Kp [M]^1.44 [Ce(IV)] ^0.55 [HAP] ^0.51. The activation energy of polymerization was found to be 17.9 kJ/mol. A probable mechanism consistent with the observed results is proposed and discussed.