Journal of Chemistry

Journal of Chemistry / 2012 / Article

Open Access

Volume 9 |Article ID 985041 | 5 pages | https://doi.org/10.1155/2012/985041

Pyridinedicarboxylic Acid Derivatives of Dichlorobis(cyclopentadienyl)titanium(IV)

Received19 Apr 2011
Accepted02 Jul 2011

Abstract

Reactions of dichlorobis(cyclopentadienyl)titanium(IV) with pyridine dicarboxylic acids viz. quinolinic acid (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Ti(QAH)Cl, Cp2Ti(QAH)2, Cp2Ti(PAH)Cl, Cp2Ti(PAH)2, Cp2Ti(IAH)Cl, Cp2Ti(IAH)2, Cp2Ti(CAH)Cl, Cp2Ti(CAH)2, Cp2Ti(DAH)Cl and Cp2Ti(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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