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Journal of Chemistry
Volume 2013, Article ID 103192, 9 pages
Research Article

Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples

Analytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416 004, India

Received 3 May 2013; Revised 21 July 2013; Accepted 22 July 2013

Academic Editor: Concha Gimeno

Copyright © 2013 Ashwini P. Gaikwad et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A simple and selective method was developed for the determination of platinum(IV) with n-octylaniline in toluene. In present study, the use of n-octylaniline in toluene for the extraction of platinum(IV) from ascorbate media was carried out. The effect of various parameters, such as pH, equilibrium time, extractant concentration, and organic solvent on the extraction has been discussed. The back extraction of platinum(IV) has been performed. On the basis of slope analysis, the composition of the extracted species was determined as [RR′NH2+ Pt(Succinate)2](org). The interfering effects of various cations and anions were also studied, and the selectivity of the method is enhanced by using suitable masking agents. The proposed method is rapid, reproducible and successfully applied for the determination of platinum(IV) in binary and synthetic mixtures. The separation of pt(IV) from other associated metals has been studied. Comparison of the results with those obtained using an atomic absorption spectrophotometer also tested the validity of the method.