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Journal of Chemistry
Volume 2013 (2013), Article ID 186168, 8 pages
http://dx.doi.org/10.1155/2013/186168
Research Article

Kinetics and Mechanism of meso-Tetraphenylporphyrin Iron(III) Chloride Catalysed Oxidation of Indole-3-Acetic Acid by Peroxomonosulphate

Department of Chemistry, Sona College of Technology, Salem 636 005, India

Received 1 December 2011; Revised 28 June 2012; Accepted 24 July 2012

Academic Editor: Guochuan Yin

Copyright © 2013 Durairaj Kungumathilagam and Kulanthaivel Karunakaran. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Mechanistic study on meso-tetraphenylporphyrin iron(III) chloride (TPP) catalysed oxidation of indole-3-acetic acid by peroxomonosulphate (oxone) in aqueous acetonitrile medium has been carried out. The reaction follows a first order with respect to both substrate and oxidant. The order with respect to catalyst was found to be fractional. The order of reaction with respect to catalyst varies with a concentration of catalyst. Increase in percentage of acetonitrile decreased the rate. The reaction fails to initiate polymerization, and a radical mechanism is ruled out. Activation and thermodynamic parameters have been computed. A suitable kinetic scheme based on these observations is proposed. Significant catalytic activity is observed for the reaction system in the presence of TPP.