Research Article
Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes
Table 1
Physical and analytical data of the complexes.
| Complexes | Colour | Mol. wt. | M.P. (°C) | Yield (% ) | % M | % C | % H | % N | B.M. | Molar cond. (−1 cm2 mol−1) |
| CrCl3(DP)3] | Pale brown | 524 | 280 | 85 | 9. 96 (10.05) | 48.21 (48.09) | 5.85 (5.72) | 13.01 (13.74) | 3.72 | 25.24 | MnCl2(DP)4] | Mercedes red | 604 | 290 | 80 | 9.05 (9.10) | 55.50 (55.62) | 6.84 (6.62) | 18.10 (18.54) | 5.35 | 23.46 | FeCl3(DP)3] | Reddish brown | 528 | 290 | 80 | 10.46 (10.60) | 48.02 (47.79) | 5.88 (5.52) | 13.20 (13.62) | 5.61 | 27.72 | CoCl2(DP)4] | Pink | 608 | 285 | 85 | 9.22 (9.70) | 55.42 (55.26) | 6.64 (6.57) | 18.24 (18.42) | 4.54 | 21.93 | NiCl2(DP)4] | Green | 607 | 278 | 85 | 9.26 (9.70) | 55.36 (55.26) | 6.68 (6.57) | 18.32 (18.45) | 2.83 | 24.42 | CuCl2(DP)4] | olive green | 612 | 275 | 85 | 10.22 (10.29) | 54.36 (54.90) | 6.86 (6.53) | 18.42 (18.30) | 1.82 | 23.58 | CdCl2(DP)4] | Colourless | 661 | 280 | 80 | 9.22 (9.70) | 55.42 (55.26) | 6.79 (6.05) | 16.80 (16.94) | — | 25.25 |
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The values of elemental analysis are found (calculated).
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