Research Article

Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes

Table 1

Physical and analytical data of the complexes.

ComplexesColourMol. wt.M.P. (°C)Yield
(% )
% M % C % H % N
B.M.
Molar cond.
( −1 cm2 mol−1)

CrCl3(DP)3]Pale brown524280859. 96
(10.05)
48.21
(48.09)
5.85
(5.72)
13.01
(13.74)
3.7225.24
MnCl2(DP)4]Mercedes red604290809.05
(9.10)
55.50
(55.62)
6.84
(6.62)
18.10
(18.54)
5.3523.46
FeCl3(DP)3]Reddish brown5282908010.46
(10.60)
48.02
(47.79)
5.88
(5.52)
13.20
(13.62)
5.6127.72
CoCl2(DP)4]Pink608285859.22
(9.70)
55.42
(55.26)
6.64
(6.57)
18.24
(18.42)
4.5421.93
NiCl2(DP)4]Green607278859.26
(9.70)
55.36
(55.26)
6.68
(6.57)
18.32
(18.45)
2.8324.42
CuCl2(DP)4]olive green6122758510.22
(10.29)
54.36
(54.90)
6.86
(6.53)
18.42
(18.30)
1.8223.58
CdCl2(DP)4]Colourless661280809.22
(9.70)
55.42
(55.26)
6.79
(6.05)
16.80
(16.94)
25.25

The values of elemental analysis are found (calculated).