Research Article

Cycloaddition Reaction of Carbon Dioxide to Epoxides Catalyzed by Polymer-Supported Quaternary Phosphonium Salts

Table 2

Cycloaddition reactions of CO2 to different epoxides.

EntryEpoxidesProductsTime (h)Selectivity (%)Yield (%)

1261378.tab.002a261378.tab.002b699.993.0
2261378.tab.002c261378.tab.002d699.498.6
3261378.tab.002e261378.tab.002f1098.695.8
4261378.tab.002g261378.tab.002h979.273.7
5261378.tab.002i261378.tab.002j4888.272.3

Reaction conditions: epoxide 3 mL, PS-QPS-1 0.08 g, 5 MPa CO2, 150°C.