Journal of Chemistry
Volume 2013 (2013), Article ID 392310, 9 pages
http://dx.doi.org/10.1155/2013/392310
Synthesis and Characterization of Metal Tribromoacetates and Their Alkali Metal Derivatives
1Centre of Advanced Studies and Department of Chemistry, Panjab University, Chandigarh 160014, India
2Chemistry Department, Mewar University, Chittorgarh, Rajasthan, India
Received 13 June 2012; Accepted 2 July 2012
Academic Editor: Elena Gomez
Copyright © 2013 Jugal Kishore Puri and Rajni Chhoker. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
Complexes of composition Fe2Cl2(O2CCBr3)4, Fe2Cl(O2CCBr3)5, Fe (O2CCBr3)3, [(Me4N)2][Fe (O2CCBr3)4], K[Fe (O2CCBr3)4], Rb[Fe (O2CCBr3)4], Cs[Fe (O2CCBr3)4], [(Me4N)2][Co(O2CCBr3)4], [(Me4N)2][Mn(O2CCBr3)4], [(Me4N)2][Cu(O2CCBr3)4], and [(Me4N)2][Ni(O2CCBr3)4] have been prepared by metathetical reactions using nitromethane as solvent. All these compounds have been characterized by elemental analysis, molar conductance, infrared, reflectance and thermogravimetric studies.