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Journal of Chemistry
Volume 2013, Article ID 392310, 9 pages
http://dx.doi.org/10.1155/2013/392310
Research Article

Synthesis and Characterization of Metal Tribromoacetates and Their Alkali Metal Derivatives

Jugal Kishore Puri1 and Rajni Chhoker2

1Centre of Advanced Studies and Department of Chemistry, Panjab University, Chandigarh 160014, India
2Chemistry Department, Mewar University, Chittorgarh, Rajasthan, India

Received 13 June 2012; Accepted 2 July 2012

Academic Editor: Elena Gomez

Copyright © 2013 Jugal Kishore Puri and Rajni Chhoker. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Complexes of composition Fe2Cl2(O2CCBr3)4, Fe2Cl(O2CCBr3)5, Fe (O2CCBr3)3, [(Me4N)2][Fe (O2CCBr3)4], K[Fe (O2CCBr3)4], Rb[Fe (O2CCBr3)4], Cs[Fe (O2CCBr3)4], [(Me4N)2][Co(O2CCBr3)4], [(Me4N)2][Mn(O2CCBr3)4], [(Me4N)2][Cu(O2CCBr3)4], and [(Me4N)2][Ni(O2CCBr3)4] have been prepared by metathetical reactions using nitromethane as solvent. All these compounds have been characterized by elemental analysis, molar conductance, infrared, reflectance and thermogravimetric studies.