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Journal of Chemistry
Volume 2013 (2013), Article ID 410304, 5 pages
http://dx.doi.org/10.1155/2013/410304
Research Article

Synthesis and Crystal Structure of 6-Bromo-2-(furan-2-yl)-3-(prop-2-ynyl)-3H-imidazo[4,5-b]pyridine

1Laboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohamed Ben Abdellah, Fès BP 2202, Morocco
2Universitat Jaume I, Departamento de Química Inorgánica y Orgánica, Avenida Sos Baynat, S/N, 12071 Castellón, Spain

Received 29 May 2013; Revised 29 July 2013; Accepted 30 July 2013

Academic Editor: Nigam P. Rath

Copyright © 2013 Youssef Kandri Rodi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The crystal and molecular structure of 6-bromo-2-(furan-2-yl)-3-(prop-2-ynyl)-3H-imidazo[4,5-b]pyridine (C13H8BrN3O) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate the molecular geometry of this compound in the solid state along with the associated intermolecular hydrogen bonding and related π-π interactions present in the crystal packing. This compound crystallizes in the monoclinic space group with cell parameters: a = 4.39655(19) Å, b = 13.5720(5) Å, c = 20.0471(5) Å, β = 94.753(3), V = 1192.10(7) Å3, D = 1.683 g·cm−3, and Z = 4. The crystal structure is stabilized by π-π interactions and intermolecular C–HN and C–HO interactions.