Table 3: Intramolecular bond angles (°) of PNP[RuIII(Pc)Cl2].

Atom Angle

N3 Ru1 N3 179.999(1)
N3 Ru1 N1 90.3(3)
N3 Ru1 Cl1 90.4(2)
N1 Ru1 Cl1 91.6(2)
N1 Ru1 Cl1 91.6(2)
N5 P1 C17 110.3(4)
N5 P1 C23 111.2(3)
C1 N1 C8 109.8(8)
C8 N2 C9122.7(8)
C16 N3 Ru1 125.7(6)
N4 C1 N1 128.8(9)
C3 C2 C7 120.0(9)
C4 C3 C2 117.9(10)
C5 C4 C3 122.2(10)
C4 C5 C6 121.2(10)
C7 C6 C5 117.3(10)
C6 C7 C2 121.4(9)
N2 C8 N1 127.7(9)
N2 C9 N3 128.3(9)
C11 C10 C15 120.9(9)
C12 C11 C10 117.3(10)
C11 C12 C13 122.0(10)
C14 C13 C12 120.2(10)
C15 C14 C13 118.5(10)
C14 C15 C10 121.1(10)
N4 C16 N3 126.1(9)
C22 C17 C18 118.3(12)
C17 C18 C19 119.0(13)
C20 C19 C18 119.4(14)
C21 C20 C19 122.7(16)
C20 C21 C22 119.0(14)
C17 C22 C21 121.6(13)
C28 C23 C24 118.8(10)
C25 C24 C23 121.6(11)
C24 C25 C26 118.8(11)
C27 C26 C25 119.2(11)
C28 C27 C26 120.7(11)
C27 C28 C23 120.8(10)
C30 C29 C34 119.9(10)
C29 C30 C31 118.9(11)
C32 C31 C30 120.4(10)
C33 C32 C31 119.4(10)
C32 C33 C34 121.6(11)
C33 C34 C29 119.7(10)
N3 Ru1 N1 89.7(3)
N3 Ru1 N1 89.7(3)
N3 Ru1 Cl1 89.6(2)
N3 Ru1 Cl1 89.6(2)
N1 Ru1 Cl1 88.4(2)
N5 P1 C29 110.5(3)
C17 P1 C23 107.7(5)
C1 N1 Ru1 124.6(6)
C9 N3 C16 108.0(8)
C1 N4 C16 124.3(8)
N4 C1 C2 122.3(9)
C3 C2 C1 133.3(9)
C4 C3 H3 121.1
C5 C4 H4 118.9
C4 C5 H5 119.4
C7 C6 H6 121.4
C6 C7 C8 132.2(9)
N2 C8 C7 124.0(9)
N2 C9 C10 122.0(9)
C11 C10 C9 133.3(10)
C12 C11 H11 121.3
C11 C12 H12 119.0
C14 C13 H13 119.9
C15 C14 H14 120.7
C14 C15 C16 132.3(10)
N4 C16 C15 123.9(9)
C22 C17 P1 119.1(9)
C17 C18 H18 120.5
C20 C19 H19 120.3
C21 C20 H20 118.7
C20 C21 H21120.5
C17 C22 H22 119.2
C28 C23 P1 122.3(8)
C25 C24 H24 119.2
C24 C25 H25 120.6
C27 C26 H26 120.4
C28 C27 H27 119.6
C27 C28 H28 119.6
C30 C29 P1 122.1(8)
C29 C30 H30 120.5
C32 C31 H31119.8
C33 C32 H32 120.3
C32 C33 H33 119.2
C33 C34 H34 120.2
N3 Ru1 N1 90.3(3)
N1 Ru1 N1 179.999(1)
N1 Ru1 Cl1 88.4(2)
N3 Ru1 Cl1 90.4(2)
Cl1 Ru1 Cl1 179.999(1)
C17 P1 C29 108.2(5)
C29 P1 C23 108.8(5)
C8 N1 Ru1 125.4(6)
C9 N3 Ru1 126.1(7)
P1 N5 P1 179.999(1)
N1 C1 C2 108.9(8)
C7 C2 C1 106.6(8)
C2 C3 H3 121.1
C3 C4 H4 118.9
C6 C5 H5 119.4
C5 C6 H6 121.4
C2 C7 C8 106.3(8)
N1 C8 C7 108.3(8)
N3 C9 C10 109.7(9)
C15 C10 C9 105.8(9)
C10 C11 H11 121.3
C13 C12 H12 119.0
C12 C13 H13 119.9
C13 C14 H14 120.7
C10 C15 C16 106.5(8)
N3 C16 C15 109.9(9)
C18 C17 P1 122.6(9)
C19 C18 H18 120.5
C18 C19 H19 120.3
C19 C20 H20 118.7
C22 C21 H21 120.5
C21 C22 H22 119.2
C24 C23 P1 119.0(8)
C23 C24 H24 119.2
C26 C25 H25 120.6
C25 C26 H26 120.4
C26 C27 H27 119.6
C23 C28 H28 119.6
C34 C29 P1 118.0(7)
C31 C30 H30 120.5
C30 C31 H31 119.8
C31 C32 H32 120.3
C34 C33 H33 119.2
C29 C34 H34 120.2