On the Difference between Self-Assembling Process of Monomeric and Dimeric Surfactants with the Same Head to Tail Ratio: A Lattice Monte Carlo Simulation

<table>Polydispersity <svg height="14.6" id="M62" style="vertical-align:-3.13504pt" version="1.1" viewbox="0 0 26.799999 14.6" width="26.799999" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.6)">
<g transform="translate(72,-60.32)">
<text transform="matrix(1,0,0,-1,-71.95,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">(</tspan>
<tspan style="font-size: 12.50px; " x="4.1634989" y="0">𝐼</tspan>
</text>
<text transform="matrix(1,0,0,-1,-61.79,60.37)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑃</tspan>
</text>
<text transform="matrix(1,0,0,-1,-54.78,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">)</tspan>
</text>
</g>
</g>
</svg> versus total volume fraction <svg height="14.7125" id="M63" style="vertical-align:-3.22281pt" version="1.1" viewbox="0 0 31.5875 14.7125" width="31.5875" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.7125)">
<g transform="translate(72,-60.23)">
<text transform="matrix(1,0,0,-1,-71.95,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">(</tspan>
<tspan style="font-size: 12.50px; " x="4.1634989" y="0">𝑉</tspan>
</text>
<text transform="matrix(1,0,0,-1,-60.6,60.37)">
<tspan style="font-size: 8.75px; " x="0" y="0">t</tspan>
<tspan style="font-size: 8.75px; " x="2.424304" y="0">o</tspan>
<tspan style="font-size: 8.75px; " x="6.730288" y="0">t</tspan>
</text>
<text transform="matrix(1,0,0,-1,-50.94,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">)</tspan>
</text>
</g>
</g>
</svg> for (H<sub>3</sub>T<sub>3</sub>)<sub>2</sub> as a double chain surfactant. From this graph CMC is estimated nearly 0.02. The slope of the graph increases after CMC.</table>

Journal of Chemistry

fig7

Figure 7

Figure 7: On the Difference between Self-Assembling Process of Monomeric and Dimeric Surfactants with the Same Head to Tail Ratio: A Lattice Monte Carlo Simulation 

Figure 7 | On the Difference between Self-Assembling Process of Monomeric and Dimeric Surfactants with the Same Head to Tail Ratio: A Lattice Monte Carlo Simulation 