Journal of Chemistry / 2013 / Article / Tab 2

Research Article

Thermal Degradation Behaviour of Ni(II) Complex of 3,4-Methylenedioxaphenylaminoglyoxime

Table 2

Kinetic parameters of Ni(HL)2 determined using the CR, HM, B, MKN, and VK equations.

Complex StageMethodParameter
(J mol−1) (s−1) (J mol−1 K−1) (kJ mol−1) (kJ mol−1)

Ni(HL)21stCR2.95 × 1053.58 × 10262.58 × 1022.90 × 1051.43 × 105
HM3.01 × 1056.43 × 10262.62 × 1022.96 × 1051.47 × 105
B3.04 × 1051.54 × 10122.332.99 × 1052.98 × 105
VK3.03 × 1055.48 × 10303.38 × 1022.98 × 1051.10 × 105
MKN2.95 × 105 4.60 × 10282.98 × 1022.90 × 1051.24 × 105
2ndCR4.01 × 1053.81 × 10−2.40 × 1023.42 × 1041.72 × 105
HM4.87 × 1055.23 × 102−2.19 × 1024.23 × 1041.58 × 105
B5.22 × 1044.12 × 10−2.21 × 1024.63 × 1042.01 × 105
VK5.06 × 1043.73 × 105−1.45 × 102 4.48 × 1041.46 × 105
MKN4.05 × 104 2.98 × 103−1.85 × 1023.47 × 1041.65 × 105
3rdCR1.04 × 1054.35 × 104−1.66 × 1029.57 × 1041.76 × 105
HM1.24 × 1054.75 × 104−1.65 × 1021.16 × 1051.77 × 105
B1.20 × 1056.32 × 102−2.01 × 1021.11 × 1053.13 × 105
VK1.24 × 1057.23 × 108−8.5 × 101.16 × 1052.01 × 105
MKN1.04 × 105 1.20 × 106−1.39 × 1029.62 × 1042.35 × 105

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