Research Article
The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study
Table 3
Effect of [OH
−], [
], and
on the reaction at 298.2 K.
| | 105 [DTC] | [Reductant] | × 102 | 103 [] | 103 [OH−] | MEE | EEE | | (mol·L−1) | (mol·L−1) | (mol·L−1) | (mol·L−1) | (mol·L−1) | 103/s−1 | 103/s−1 |
| | 7.16 | 0.03 | 3.80 | 1.00 | 5.00 | 7.17 | 8.20 | | 7.16 | 0.03 | 3.80 | 1.00 | 10.00 | 7.94 | 9.69 | | 7.16 | 0.03 | 3.80 | 1.00 | 15.00 | 8.27 | 10.18 | | 7.16 | 0.03 | 3.80 | 1.00 | 20.00 | 8.45 | 10.68 | | 7.16 | 0.03 | 3.80 | 1.00 | 25.00 | 8.53 | 10.86 | | 7.16 | 0.03 | 3.80 | 0.50 | 2.50 | 9.49 | 13.24 | | 7.16 | 0.03 | 3.80 | 1.00 | 2.50 | 7.13 | 10.14 | | 7.16 | 0.03 | 3.80 | 1.50 | 2.50 | 5.84 | 7.54 | | 7.16 | 0.03 | 3.80 | 2.00 | 2.50 | 4.90 | 6.73 | | 7.16 | 0.03 | 3.80 | 2.50 | 2.50 | 4.27 | 5.86 | | 7.16 | 0.03 | 1.50 | 1.00 | 2.50 | 8.89 | 12.34 | | 7.16 | 0.03 | 3.00 | 1.00 | 2.50 | 7.56 | 9.61 | | 7.16 | 0.03 | 4.50 | 1.00 | 2.50 | 7.03 | 9.17 | | 7.16 | 0.03 | 6.00 | 1.00 | 2.50 | 6.45 | 8.68 | | 7.16 | 0.03 | 7.50 | 1.00 | 2.50 | 5.19 | 7.66 |
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