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Journal of Chemistry
Volume 2013 (2013), Article ID 742915, 7 pages
http://dx.doi.org/10.1155/2013/742915
Research Article

Spectroscopic and Biological Studies on Newly Synthesized Cobalt (II) and Nickel (II) Complexes with 2-Acetyl Coumarone Semicarbazone and 2-Acetyl Coumarone Thiosemicarbazone

1Department of Chemistry, Government Science & Commerce College, M.P. Bhoj (open) University, Benazeer, Bhopal 462016, India
2Department of Chemistry, Zakir Husain Delhi College, University of Delhi, Jawaharlal Nehru Marg, New Delhi 110002, India

Received 13 June 2012; Accepted 1 October 2012

Academic Editor: Filomena Conforti

Copyright © 2013 Sanjay Goel et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Co(II) and Ni(II) complexes of general composition ML2X2 (M = Co(II), Ni(II); X = Cl, ) were synthesized by the condensation of metal salts with semicarbazone/thiosemicarbazone derived from 2-acetyl coumarone. The ligands and metal complexes were characterized by NMR, elemental analysis, molar conductance, magnetic susceptibility measurements, IR, and atomic absorption spectral studies. On the basis of electronic, molar conductance and infrared spectral studies, the complexes were found to have square planar geometry. The Schiff bases and their metal complexes were tested for their antibacterial and antioxidant activities.