Journal of Chemistry

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Molecular Modeling: Advancements and Applications

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Research Article | Open Access

Volume 2013 |Article ID 948010 | https://doi.org/10.1155/2013/948010

Sattar Arshadi, Ameneh Asghari, Hojatollah Raheimi, Saboora Abedini, "Influence of Pyrazine Ring Doping on the 15N and 11B NMR and Electronic Structure Parameters in Zigzag Boron Nitride Nanotube: A DFT Study", Journal of Chemistry, vol. 2013, Article ID 948010, 10 pages, 2013. https://doi.org/10.1155/2013/948010

Influence of Pyrazine Ring Doping on the 15N and 11B NMR and Electronic Structure Parameters in Zigzag Boron Nitride Nanotube: A DFT Study

Academic Editor: André Silva Pimentel
Received24 Jun 2012
Accepted18 Nov 2012
Published11 Dec 2012

Abstract

Density functional theory (DFT) calculations have been performed to investigate the properties of the electronic structures of pyrazine-doped boron nitride nanotubes (PD-BNNTs). The structural forms were firstly optimized and then nuclear magnetic resonance (NMR) parameters have been calculated on the optimized structures. The chemical shielding isotropic () and chemical shielding anisotropic () parameters were calculated at the sites of 11B and 15N nuclei in structural forms of BNNT including the perfect (a) model and PD-BNNTs (b), (c), and (d) models. The results indicated that the changes are most significant for those nuclei placed in the nearest neighborhood of the pyrazine-doped ring. The changes of the electronic sites of the N atoms are also more significant than those of the B atoms. The difference of LUMO-HOMO gap for the perfect model was larger than the PD-BNNTs models. Also the atomic charge distribution of N and B atoms has been determined in nanotubes by natural bond orbital (NBO) analysis. All calculations were performed by the B3LYP method and 6-311G** basis set using Gaussian 98 package of program.

1. Introduction

The existence of tubular forms of matter with nanoscale diameters has opened an exciting field of research in science. Since the discovery of carbon fullerene C60 by Smalley et al. in 1985 and carbon nanotubes by Iijima in 1991, electronic and mechanical properties of carbon and noncarbon nanotubes have been investigated by various groups [14].

Boron nitride (BN) is the first candidate to replace carbon, because hexagonal-BN structure is quite similar to that of graphite. Boron nitride nanotubes (BNNTs) have attracted an enormous amount of attention [513] as a typical representative of III–V compound tubes, partially because they have the morphology of honeycomb analogous to carbon nanotubes (CNTs). It has been shown that BNNTs exhibit many interesting properties such as significant resistance to oxidation at high temperatures when compared to the carbon nanotubes [1419].

Unlike CNTs, all BN nanotubes exhibit semiconducting behavior with a wide band gap which is almost independent of tubular diameter, chirality, and number of walls [6, 20]. Furthermore, in contrast to the nonpolar CNTs, slight positive charge of boron atom (B) and slight negative charge of nitrogen atom (N) increase the polarity and the ionicity of the BNNTs. Therefore, the BNNTs have been proposed as more proper materials than the CNTs for applications in the specific electronic and mechanical devices.

The structure of BNNTs was firstly predicted by theoretical calculations [7, 21]. In 1995, Chopra et al. [5] reported the production of multiwalled BNNTs using arc-discharge techniques. The other synthesis methods are laser-assisted technique [22, 23] using pyrolytically grown CNTs as templates to prepare BNNTs, using chemical vapor deposition (CVD) by Lourie et al. [24]. In 2001, Bengu and Marks proposed a new method to synthesize the single-walled BN nanotubes [25]. This new synthesis technique has made it possible to bring BN nanotubes into the nanotechnology applications.

Previous studies have indicated that the properties of the electronic structure of the BNNTs are influenced by the doping atoms and impurities. Thus, uniformly doped BNNTs obtained through chemical modification could be very effective for tailoring the electronic properties, and the related mechanism and behavior are valuable to be explored in theory [26, 27].

Within present research, we have investigated the electronic structures and NMR parameters at the sites of 11B and 15N nuclei of perfect and pyrazine-doped models of BNNTs by density functional theory (DFT) calculations. Furthermore, we have investigated atomic charge distribution in nanotubes by natural bond orbital (NBO) [28] analysis.

2. Models and Computational Methods

Conveniently, BN nanotube could be presented by a (, ) pair of numbers, where the (, 0) and (, ) BN nanotubes designate the zigzag and armchair types, respectively. For the zigzag type BN nanotube, n denotes the number of triazines in the circumference of the tube and the translation axis is the tubular length.

We have considered four models: a perfect and three pyrazine-doped models in Figures 1(a)1(d) of the representative (6,0) zigzag single-walled BNNTs in present study. Figure 1(a) shows the perfect model, which consists of 24 boron (B) atoms and 24 nitrogen (N) atoms where the two tips of the nanotube are saturated by 12 hydrogen (H) atoms. In the perfect zigzag BNNTs, three B and three N atoms in the center of nanotube have been replaced by four carbon atoms (sp2-hybridized) and two N atoms to create the pyrazine-doped BNNTs (pyrazine-BNNTs). Figures 1(b)1(d) show three doped models which have different position for pyrazine ring in corresponding models.

In the first step, the structures have been allowed to relax by all atomic geometrical optimization at the DFT level with B3LYP exchange-functional method and 6-311G** basis set. Furthermore NBO analysis was carried out on the B3LYP/6-311G** wave functions using version 3.1 of NBO package [29] included in Gaussian 98 program package [30].

Also we investigated electronegativity () in the optimized structures. As we already know, electronegativities may be considered as the power of an atom in a given molecule to attract electrons to itself [31]. For an N-electron system with potential acting on an electron at due to the nuclear attraction plus such other external forces as may be present (external potential) and total energy , electronegativity () [32] is defined as the following:

The electronegativity is defined as the half part of the difference between the HOMO and the LUMO energies as follows:

The CS tensors are calculated for optimized nanotubes at the DFT level employing the B3LYP method and 6-311G** basis set based on the gauge independent atomic orbital (GIAO) approach [33]. The calculated CS tensors at the sites of 11B and 15N are yielded in the principal axes system (PAS) [34]. Thereafter, they are converted to isotropic chemical shielding () and anisotropic chemical shielding () parameters using (3) [35] and are showed in Tables 5, 6, and 7: The DFT calculations have been performed by the Gaussian 98 package.

3. Results and Discussion

3.1. The Optimized Parameters

At the first step of this task, structural optimization was successfully carried out for the perfect ((a) model) and doped models ((b), (c), and (d) models) of the single-wall (6, 0) BNNT at the level of B3LYP, DFT method and 6-311G** basis set.

Subsequently, frequency calculations (keyword: ) were carried out by standard techniques on the optimized structures. For minimum state species, only real frequency values (with a positive sign) are accepted.

Table 1 presents the results for structural energies, the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO), LUMO-HOMO gaps, dipole moments, and electronegativity obtained by the DFT calculations.


ModelsEnergy (keV) (eV) (eV)Δ(LUMO-HOMO) (eV)Dipole moment (Debye)Electronegativity ( )

Perfect (a)−52.22−1.99−6.854.867.474.42
(b)−52.85−1.86−4.893.038.273.37
(c)−52.85−2.13−4.702.576.933.41
(d)−52.85−2.13−4.702.576.933.41

Our results indicated that the values of LUMO-HOMO gaps of the PD-BNNTs models are smaller than the perfect model. Also among the values of the LUMO-HOMO gaps of the pyrazine-doped models, the most significant changes were observed for the c and d models.

As we know, the band gap for the BN nanotube is higher in energy than the CNTs [6]. On the other hand, pyrazine-doped BN nanotube has similarities to CNTs in view of the prescience of carbons in the nanotube wall. Therefore the band gap in pyrazine-doped BN nanotube is similar to CNTs to some extent. This is proved by the calculated energies which are shown in Table 1.

The LUMO-HOMO gap is 4.86 eV for perfect model, 3.03 eV for (b) model, and 2.57 eV for (c) and (d) models, respectively (Table 1).

Also the densities of states (DOSs) of perfect and pyrazine-doped BNNT are shown in Figure 2 for better understanding the effect of pyrazine ring doping on the electronic structure of BNNT. It is clear that, after doping of pyrazine ring, the HOMO-LUMO energy gap of tube has significant change. On the other hand, the doping of pyrazine ring decreases the HOMO-LUMO energy gaps of the perfect BNNT.

The HOMO and LUMO in the perfect and pyrazine-doped models are plotted in Figure 3. For the perfect model, the HOMO is located on the nitrogen atoms of the (6, 0) zigzag BNNT model and corresponds to the lone pair of electron on nitrogen atoms. In contrast, the LUMO is uniformly distributed throughout the B–N bonds. For the pyrazine-doped models, the majority of the HOMO and LUMO are located at the pyrazine-doped regions.

The circumferences of the armchair BNNTs include both N and B atoms in both ends. In contrast to armchair models, circumferences of the zigzag BNNTs consist of one-type atoms, either N or B atoms; if one of the ends is formed by N atoms, the other end is formed by B atoms. The B atoms are slightly positive and the N atoms are slightly negative; therefore, the zigzag BNNT is a polar material that could be better seen by the value of dipole moment. Comparing the values of the dipole moments for the four models indicates that the value for the (b) model is significantly increased ( Debye) whereas those for the (c) and (d) models are significantly reduced ( Debye) compared with the perfect (a) model ( Debye), which means that the strengths of the charge points are balanced in the two latter models (Table 1).

The calculated structural energies in Table 1 also indicate no difference between the three models of the PD-BNNTs ( keV). On the other hand, the (c) and (d) models are structural isomers of the (b) model.

Tables 2, 3, and 4 present the optimized parameters including the bond lengths and bond angle for four models of the investigated (6, 0) BNNT (Figures 1(a)1(d)).


BondsLength ( )BondsLength ( )BondsLength ( )BondsAngle (°)BondsAngle (°)

B41–N441.45 1.45 B42–n41.44 1.45 B43–N411.45 1.45 c2–n1–c6113 118 B23–c6–c5119 118
B41–N331.45 1.45 B42–N421.45 1.45 c5–N311.42 1.46 c3–c2–n1117 118 c5–N31–B43119 118
B41–N431.45 1.45 c3–n41.43 1.46 B34–N311.46 1.46 c2–c3–n4120 120 c3–n4–B42119 118
B31–N331.46 1.46 c5–n41.43 1.46 c5–c61.35 1.45 c3–n4–c5109 111 c5–n4–B42119 118
c3–N331.42 1.46 c2–c31.35 1.45 c6–B231.54 1.46 n4–c5–c6120 120 B41–N33–c3119 118
B31–N241.44 1.46 c2–n11.44 1.46 B23–N111.43 1.45 c5–c6–n1117 118 c3–N33–B31115 111
B21–N241.45 1.45 n1–N121.42 1.45 B23–N211.45 1.45 B23–c6–n1116 110 c5–N31–B34115 111
B21–N131.43 1.45 C6–n11.44 1.46 B13–N111.46 1.46 B21–c2–n1116 110 N24–B21–c2117 118
c2–B211.54 1.45 B12–N121.46 1.46 B14–N111.46 1.46 B21–c2–c3119 118 c6–B23–N21117 118
B11–N131.46 1.46 B13–N121.46 1.46 B34–N211.44 1.46 n4–c5–N31116 118 c6–B23–N11119 120
B12–N131.46 1.46 B43–N421.45 1.45 B14–N161.46 1.46 N33–c3–n4116 118 c2–B21–N13119 120
B42–N431.45 1.45 B43–N311.45 1.45 B15–N161.46 1.46 c6–c5–N31121 120 c2–c3–N33121 120


BondsLength ( )BondsLength ( )BondsLength ( )BondsAngle (°)BondsAngle (°)

B41–N441.46 1.45 c2–B421.52 1.45 B43–N411.46 1.45 c6–c5–n4121 118 B23–n4–c3119 118
B41–N331.44 1.45 B42–N421.45 1.45 c3–N311.42 1.46 n1–c6–c5121 118 c3–N31–B43118 118
B41–N431.46 1.45 n1–c21.47 1.46 B34–N311.48 1.46 c6–n1–c2115 120 n1–c2–B42117 118
B31–N331.46 1.46 c2–c31.36 1.46 c3–n41.40 1.45 n1–c2–c3120 111 c3–c2–B42121 118
n1–N331.49 1.46 c6–n11.40 1.45 n4–B231.46 1.46 c2–c3–n4122 120 B41–N33–n1115 118
B31–N241.44 1.46 c5–c61.38 1.46 B23–N111.43 1.45 c3–n4–c5115 118 n1–N33–B31117 111
B21–N241.46 1.45 c5–N121.41 1.45 B23–N211.44 1.45 B23–n4–c5114 110 c3–N31–B34110 111
B21–N131.45 1.45 c5–n41.44 1.46 B13–N111.45 1.46 B21–c6–c5107 110 N24–B21–c6115 118
c6–B211.53 1.45 B12–N121.47 1.46 B14–N111.46 1.46 B21–c6–n1123 118 n4–B23–N21108 118
B11–N131.46 1.46 B13–N121.45 1.46 B34–N211.44 1.46 c2–c3–N31120 118 n4–B23–N11119 120
B12–N131.44 1.46 B43–N421.44 1.45 B14–N161.45 1.46 N33–n1–c2106 118 c6–B21–N13120 120
B42–N431.45 1.45 B43–N311.47 1.45 B15–N161.46 1.46 n4–c3–N31118 120 c6–n1–N33114 120


BondsLength ( )BondsLength ( )BondsLength ( )BondsAngle (°)BondsAngle (°)

B41–N441.46 1.45 c6–B421.52 1.45 B43–N411.46 1.45 n4–c3–c2121 118 B23–c2–n1123 118
B41–N331.47 1.45 B42–N421.45 1.45 n1–N311.49 1.46 c5–n4–c3115 118 n1–N31–B43115 118
B41–N431.44 1.45 c5–C61.36 1.46 B34–N311.46 1.46 n4–c5–c6122 120 c5–c6–B42121 118
B31–N331.48 1.46 c6–N11.47 1.46 n1–c61.47 1.45 c5–c6–n1120 111 n1–c6–B42117 118
c5–N331.42 1.46 c5–n41.40 1.45 c2–B231.53 1.46 c6–n1–c2115 120 B41–N33–c5117 118
B31–N241.44 1.46 c3–n41.44 1.46 B23–N111.45 1.45 n1–c2–c3121 118 c5–N33–B31110 111
B21–N241.44 1.45 c3–N121.41 1.45 B23–N211.46 1.45 B23–c2–c3107 110 n1–N31–B34117 111
B21–N131.43 1.45 c2–c31.38 1.46 B13–N111.44 1.46 B21–n4–c3114 110 N24–B21–n4118 118
n4–B211.46 1.45 B12–N121.45 1.46 B14–N111.46 1.46 B21–n4–c5119 118 c2–B23–N21115 118
B11–N131.46 1.46 B13–N121.47 1.46 B34–N211.44 1.46 c6–n1–N31106 118 c2–B23–N11120 120
B12–N131.45 1.46 B43–N421.46 1.45 B14–N161.46 1.46 N33–c5–c6120 118 n4–B21–N13119 120
B42–N431.45 1.45 B43–N311.44 1.45 B15–N161.45 1.46 c2–n1–N31114 120 n4–c5–N33118 120


CSI (ppm)CSA (ppm)CSI (ppm)CSA (ppm)
NucleiNuclei
PerfectDopedPerfectDopedPerfectDopedPerfectDoped

Layer 1Layer 1
 B16460N175242
 B116559N1189257
 B127454N1228194
 B137454N1389257
 B146559N1473244
 B156460N1573238
 B166460N1673244
Layer 2Layer 2
 B26943N2111195
 B216955N21105209
 B22N22
 B236955N23
 B247044N24105209
 B256944N25110195
 B267044N26110195
Layer 3Layer 3
 B36939N3115187
 B316840N31115124
 B32N3210192
 B33N33115124
 B346840N34115188
 B357038N35113187
 B367038N36115188
Layer 4Layer 4
 B47046N414894
 B417439N4115386
 B427744N4216374
 B437439N4316374
 B447144N4415386
 B456946N4514798
 B467144N4614798


CSI (ppm)CSA (ppm)CSI (ppm)CSA (ppm)
NucleiNuclei
PerfectDopedPerfectDopedPerfectDopedPerfectDoped

Layer 1Layer 1
 B16460N175242
 B116657N1188241
 B127354N1259224
 B137054N1376263
 B146558N1475245
 B156459N1574243
 B166458N1674242
Layer 2Layer 2
 B26943N2111195
 B217549N21115195
 B22N22112137
 B237442N23
 B246845N24119199
 B256943N25110198
 B267044N26110194
Layer 3Layer 3
 B36939N3115187
 B317042N31114136
 B32N32
 B33N336497
 B346842N34113182
 B356841N35115188
 B366941N36113184
Layer 4Layer 4
 B47046N414894
 B417444N4115192
 B427057N42141119
 B437047N4315294
 B447045N4415577
 B457045N4514994
 B467045N4614895


CSI (ppm)CSA (ppm)CSI (ppm)CSA (ppm)
NucleiNuclei
PerfectDopedPerfectDopedPerfectDopedPerfectDoped

Layer 1Layer 1
 B16460N175242
 B116558N1176263
 B127054N1259224
 B137354N1388241
 B146657N1474242
 B156458N1574243
 B166459N1675245
Layer 2Layer 2
 B26943N2111195
 B217442N21119199
 B22N22
 B237549N23112137
 B247044N24115195
 B256943N25110194
 B266845N26110198
Layer 3Layer 3
 B36939N3115187
 B316842N316497
 B32N32
 B33N33114136
 B347042N34113184
 B356941N35115188
 B366841N36113182
Layer 4Layer 4
 B47046N414894
 B417047N4115577
 B427057N4215294
 B437444N43141119
 B447045N4415192
 B457045N4514895
 B467045N4614994

In the perfect BNNT (Figure 1(a)), the average B–N bond length was 1.45-1.46 Å, but this value also was changed by the pyrazine-doping in the PD-BNNT due to existence of B–C, C–N, N–N, and C=C bonds in addition to B–N one.

However, the effects of this deformation were significant just at the geometrical properties of the nearest atoms to the pyrazine-doped ring whereas those of other atoms almost remained unchanged. Furthermore, the changes of the bond angles were more than those of the bond lengths in the zigzag PD-BNNT.

Among theoretical methods, natural bond orbital (NBO) analysis is a unique approach to the evaluation of the atomic charges. It is clear that the charges of N and B atoms in these structures are negative and positive, respectively. The charges of N and B atoms at the end of tubes are smaller than those of other ones. Moreover, the results of NBO analysis indicated that the atomic charge distribution in the pyrazine-doped models is different from the perfect model.

3.2. NMR Parameters

In this computational work, the CS tensors ( and ) for various 11B and 15N atoms are calculated to study the influence of pyrazine ring doping on the electronic structure properties of the (6, 0) BNNT.

In the following text, the calculated 11B and 15N NMR parameters for the perfect and the pyrazine-doped models of BNNT are discussed, respectively.

3.2.1. The Perfect Model

Tables 5, 6, and 7 present the calculated NMR parameters for various 11B and 15N nuclei in the perfect model of BNNT. This model includes 24 B and 24 N atoms, where the edges are saturated by 12 H atoms (Figure 1(a)).

A quick look at the results reveals that various 11B and 15N nuclei are divided into four layers along the nanotube length. The layers have equivalent calculated and parameters, which means that the nuclei in each layer have equivalent electrostatic properties around similar nuclei.

The nature of the valence shells of the N atoms, which have lone pair of electrons, and the B atoms, which have a lack of electrons, is different; therefore, different behavior of the CS properties is expected and is also observed for these atoms.

The values of NMR properties for the 11B and 15N nuclei of the perfect model indicate that the B-mouth (B1) has the smallest value of (11B), 64 ppm, and the N-mouth (N4) has the largest value of (15N), 148 ppm, among the other layers of nuclei.

In contrast, the opposite behavior is observed for the values of : the B-mouth has the largest value of (11B), 60 ppm, whereas the N-mouth has the smallest value of (15N), 94 ppm, among the other layers of nuclei.

3.2.2. The PD-BNNT Models

In the doped models, three B and three N atoms are doped by four carbon atoms (sp2-hybridized) and two N atoms to construct PD- BNNTs ((b), (c) and (d)) models of Figure 1.

Due to this doping, the CS tensors at the sites of 11B and 15N nuclei which are directly bonded to the pyrazine ring undergo significant changes among the other nuclei in comparison with the perfect model. Furthermore, the magnitude of changes of the CS tensors is more significant at the sites of 15N nuclei than at those of 11B nuclei.

Although the other not directly bonded B and N layers are influenced by the pyrazine-doped ring, due to the sensitivity of the CS tensors, they also undergo some minor changes in the doped model. Moreover, the CS tensors at the sites of those nuclei shown in Figures 1(b)1(d) (front side) change while those at the other side (back side) do not undergo any significant changes and their NMR parameters remain unchanged as those of the perfect model.

For example, in the (b) model (Figure 1(b)), NMR parameters of B42 (directly bonded) and B41, B43 (indirectly) were influenced by the pyrazine-doping whereas those of B44, B45, and B46 undergo some minor changes.

The evaluated NMR parameters at the sites of 11B and 15N nuclei in the perfect and doped models are presented in Tables 5, 6, and 7. In the (b) model of the zigzag PD-BNNT (Figure 1(b)), B32, B33, N22, and N23 atoms are doped by the C atoms and B22 and N32 atoms are doped by the N atoms which yield B–C, C–N, N–N, and C=C bonds. The results indicated that the changes are most significant for those nuclei placed in the nearest neighborhood of the pyrazine-doped ring.

In the first layer, N12 has the smallest and values (28 and 194 ppm, resp.) among the remaining N atoms in this layer. Also the calculated results show that those N atoms (N41, N42, N43, and N44) have the largest values (153, 163, 163, and 153 ppm) but the smallest values (86, 74, 74, and 86 ppm) among all N atoms.

The changes in the values of the CS parameters for B12, B13, B41, B42, and B43 atoms are also notable (Table 5).

The doping of B22, B33, N23, and N32 atoms by the C atoms and the doping of B32 and N22 atoms by the N atoms take place in the (c) model of the zigzag PD-BNNT (Figure 1(c)) which yield B–C, C–N, N–N, and C=C bonds.

Among the B atoms of the (c) model, B21, B23, and B42 are directly bonded to the pyrazine ring; hence, their NMR parameters ( or ) detect some changes due to the pyrazine-doping. Moreover, the NMR parameters of atoms further away show minor changes.

The and values for the N nuclei in the (c) model are different from those values in the (b) model. However notable changes in the CS tensors are observed for all of the N atoms due to the direct and indirect effect of the pyrazine-doped ring (Table 6).

In the (d) model (Figure 1(d)), B22, B32, N22, and N32 atoms are doped by the C atoms and B33 and N23 atoms are doped by the N atoms.

The NMR parameters at the sites of 11B, 15N nuclei in (d) model are quite similar with the (c) model (Tables 6 and 7).

4. Conclusion

We have investigated the properties of the electronic structure of the pyrazine-doping in the BNNTs by performing the DFT calculations. The geometries were optimized at the B3LYP/6-311G** level of theory. The structural energies, LUMO-HOMO gaps, dipole moments, and electronegativity () for perfect model and doped models have been calculated. The results of the perfect and doped models reveal some remarkable trends.

First, the optimization process reveals that BN nanotube surface is not smooth like CNTs but the N nuclei were relaxed outward and the B nuclei were relaxed inward of the nanotubes surface. Second, the values of dipole moments and band gaps are changed in the pyrazine-doped models. Third, the average B–N bond length in the (6,0) perfect BNNT was 1.45-1.46 Å, but this value was changed in the PD-BNNTs. Fourth, in the perfect model, the NMR parameters can divide BNNT structure into equivalent layers in which the B-mouth (B1) has the smallest but the N-mouth (N4) has the largest among the B and N layers, respectively.

Fifth, the results indicated the changes of NMR parameters are significant just for those atoms placed in the nearest neighboring of the pyrazine-doped ring. Clearly, pyrazine ring doping effect is totally different from Carbon impurity effect on electrostatic properties of BNNTs [36].

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Copyright © 2013 Sattar Arshadi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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