Review Article
Effects of Surfactants on the Rate of Chemical Reactions
Table 1
Parameters obtained from stoichiometric model for interaction of ME
2+ with SDS at 283–303 K [
83].
| | (K) | Region | sc
(mM) |
(M−1 min−1) | Samiey equation | | | | Cooperativity |
| | 283 | 1st | 0.0 | 110.75 | | 2552.2 | 4.28 | 1.33 |
− | | | 2nd | 0.97 | 39.00 | | 1030.7 | 4.22 | 1.49 |
− | | 3rd | 4.80 | 7.51 | | 206.4 | 2.38 | 1.11 | |
| | 293 | 1st | 0.0 | 246.00 | | 2391.0 | 4.07 | 1.29 |
− | | | 2nd | 0.97 | 95.29 | | 925.7 | 3.88 | 1.41 |
− | | 3rd | 4.80 | 21.63 | | 167.8 | 2.46 | 1.24 | |
| | 303 | 1st | 0.0 | 516.88 | | 1863.5 | 3.75 | 1.24 |
− | | | 2nd |
0.97 | 253.66 | | 883.6 | 3.75 | 1.38 |
− | | 3rd | 4.80 | 65.05 | | 177.5 | 2.54 | 1.28 | |
|
|
Dimension of is in kJ (mol molar(surfactant))−1. Dimension of SDS concentration in the Samiey equation is in M. Dimension of is in .
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