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Journal of Chemistry
Volume 2015, Article ID 138202, 5 pages
http://dx.doi.org/10.1155/2015/138202
Research Article

Intermittent Plurisink Model and the Emergence of Complex Heterogeneity Patterns: A Simple Paradigm for Explaining Complexity in Soil Chemical Distributions

1Department of Applied Mathematics, ETSI Agrónomos, Universidad Politécnica de Madrid, Avenida Complutense s/n, 28040 Madrid, Spain
2Department of Applied Mathematics, ETSI Informáticos, Universidad Politécnica de Madrid, Campus de Montegancedo s/n, Boadilla del Monte, 28660 Madrid, Spain

Received 31 March 2015; Accepted 16 April 2015

Academic Editor: Jianchao Cai

Copyright © 2015 Miguel Ángel Martín et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The spatial complexity of the distribution of organic matter, chemicals, nutrients, and pollutants has been demonstrated to have multifractal nature. This fact supports the possibility of existence of some emergent heterogeneity structure built under the evolution of the system. The aim of this paper is providing a consistent explanation of the mentioned results via an extremely simple model.

1. Introduction: Searching Explanations for Soil Heterogeneity

Heterogeneity and complexity are ubiquitous at all scales in soil and hydrologic systems. Nowadays, new technologies are of an invaluable help for providing a great number of highly calibrated field measurements. One can get a huge amount of data from computer tomography of soil samples at microscopic scales, digital terrain catchments of landscapes, and river basins among many other technological tools. Then mathematical tools are needed to analyse and interpret those data as well to construct models to predict. However, along the way needed to get such a final purpose, scientists also need to understand why the heterogeneity is produced and what the organizing principles that might underlie the heterogeneity and complexity are (McDonnell et al. [1]). Also it is encouraged to explore the scaling behaviour of heterogeneity and the emergent properties in soil and hydrologic systems. In this paper we are mainly interested in some aspects concerning the heterogeneity in the soil scenario.

Certainly we believe that the above understanding, besides providing coherence to science, also may be useful to get the practical purpose itself. In the case of soil, an illustrating example supporting this and the issues mentioned above is the study of soil texture heterogeneity. On one hand, Multifractal Analysis of fine granulometry soil data obtained by laser diffraction techniques provides information about the scaling behaviour of particle size distribution (PSD) heterogeneity (Montero [2]). In a second step, models able to replicate the heterogeneity formerly shown may be useful for prediction purposes (Martín and García-Gutiérrez [3]). The answer to why such heterogeneity exists, however, is not an easy issue since different sources of heterogeneity should be expected. In Frisch and Sornette [4] and Sornette [5], it is suggested that the fractal behaviour might be the result of a natural mixing of simple multiplicative process that takes place along the fragmentation of different particles, also pointing out that there is no accepted theoretical explanation. Recently fragmentation algorithms were proposed to replicate the multifractal nature of soil PSD (Martín et al. [6]). In this respect it is needed to say that any partial, but coherent, explanation should help to understand the (possibly several ones) organizing principles involved.

On the other hand, the spatial complexity of the distribution of organic matter, chemicals, nutrients, and pollutants has been studied by different authors (Kravchenko et al. [7], Lehmann et al. [8]). Multifractal Analysis has been successfully used to study the spatial variability of chemicals and organic matter contents, which is characterized by the generalized fractal dimensions (Kravchenko et al. [7]). Searching why such structured heterogeneity exists, a reducionist approach based in the description of transport equations in soil, seems an unlikely choice to describe the emergence of such complex pattern across the spatial scales. On the contrary, an explanation based on the fact that many complex systems in nature evolve in an intermittent burst-like way rather than in a smooth gradual manner (Rodríguez-Iturbe and Rinaldo [9]) would be more adequate. Further, such a kind of structured heterogeneity is commonly interpreted as the result of chaos or self-organization which leads to the emergent structure built under the evolution of the system (Sornette [5]). The aim of this paper is to provide a small contribution via an extremely simple model, which gives a consistent explanation to the mentioned results on spatial variability of chemicals or pollutants in soil.

The paper is organized as follows. In Section 2.1 the model is presented and in Section 2.2 the entropy scaling analysis method is described. Section 3 is devoted to analysing the results obtained in different simulations and their discussion.

2. Material and Methods

2.1. The Model

Let us suppose that is a soil area square-shaped. Suppose further that at any of the four corners there is a sink () randomly acting in an intermittent manner. Suppose each sink acting with relative frecuency be the relative frequency of the appearance of such action. A pollutant deposit (“pollutant seed”) is supposedly located in an arbitrary point of the square. When a given sink acts, its suction action is able to attract the pollutant matter to another point reducing the distance to the sink in a factor , where the pollutant rests until a new (or the same) sink acts. This factor reflects the mean value of the suction power of the respective sinks. However, the “flying” pollutant matter leaves a unit of pollutant at any point where the pollutant “rests” along its travelling.

Although a much more sophisticated model might be constructed for a more realistic performance under the same essential idea, we rather prefer to emphasize how complexity may appear under quite simple and natural actions evolving in time.

2.2. Measuring Heterogeneity

When the model is implemented a first goal is applying mathematical tools in order to parameterize heterogeneity in a reliable manner.

For simplicity let us assume that the unit square in the plane is the support of a distribution with highly heterogeneous features. In order to scrutinize its heterogeneity, let us consider a collection (mesh) of   -boxes, , of side length , representing a partition of for each value , (see Figure 1).

Figure 1: Partition of the support by squares of side length .

When the mass inside any box is known, the Shannon entropy (Shannon [10]) of with respect to a fix partition is given byprovided if .

The number is expressed in information units (bits) and its extreme values are , which corresponds to the most even (homogeneous) case—where all the squares have the same cumulative mass—and 0, which corresponds to the most uneven (heterogeneous) case—where the whole mass is concentrated in a single square. The Shannon entropy is a widely accepted measure of evenness or heterogeneity in the mass distribution at the scale level given by each partition . In fact, it can be shown that any measure of heterogeneity with the natural properties for such goal must be a multiple of (Khinchin [11]).

Using increasing values of (decreasing values of ) one can obtain an increasing amount of information about the distribution as grows to infinity. If such an increase is not erratic but rather conforms to a scaling or asymptotic behaviour of when , then the entropy or information dimension of is defined (Rényi [12]) by means of the equationwhere “” means that will linearly fit .

3. Results and Discussion

In order to implement the model, different set of values of and were selected (). First close values of were used under the assumption of similar intermittent frequencies, while the values used try to investigate the effect of relative different suction powers. For any simulation the centre of the square has been chosen as initial position for the “pollutant seed.” Then for any simulation a scaling entropy analysis has been made following Section 2.2.

Figures 2(a) and 2(b) show two different simulations of 500 points for the same and values (, , , , , , , and ). The scaling analysis was made by using values from to . The mass is given by the proportion of points inside any box . The value of is plotted against and a linear fitting is implemented. The slope of the regression line gives an estimation of the entropy dimension with value as coefficient of determination. It can be noticed that the physical appearance of both simulations is quite different, thus illustrating the high influence of the random effect in this case. Also the scaling analysis reveals different results ( and values) for both simulated distributions. For the same and values, simulation of 20000 points leads to the results in Figures 3(a) and 3(b).

Figure 2: Two distributions generated with 500 points and the same probabilities and factors (, , , , , , , and ).
Figure 3: Two distributions generated with 20000 points and the same probabilities and factors (, , , , , , , and ).

Table 1 shows the results of this analysis. It is observed that the influence of the random component diminishes for increasing number of points used in the simulation. Also the values become closer to 1. Figure 4 shows the value of the estimated entropy dimension for increasing number of points. Table 2 shows data involved in that figure.

Table 1
Table 2
Figure 4: Value of the estimated entropy dimension for increasing number of points .

Results clearly show the emergence of a mass distribution with a well-defined structured heterogeneity that the scaling analysis reveals. In fact the robustness of the results is based on a theorem of ergodic type (Elton [13]).

Finally Figures 5(a), 5(b), and 5(c) show the result of 20000 points simulation with the same probabilities and different values of the factors .

Figure 5: Distributions generated with 20000 points, the same probabilities, and different factors.

Table 3 shows the value of the estimated entropy dimension. The values obtained reflect the scale invariance of the resulting distributions.

Table 3

Smaller values representing greater suction powers have obvious influence on the heterogeneity of the final distribution which remains parameterized by the entropy dimension. In an intuitive sense, the entropy dimension value may be interpreted as uncertainty degree. In fact it can be used together with other parameters in interpolation procedures in soil spatial variability studies (Kravchenko et al. [7]).

4. Conclusions

Heterogeneity is ubiquitous in many soil scenarios. In particular the spatial complexity of the distribution of organic matter, chemicals, nutrients, and pollutants is a frequent ingredient, which is in the focus of soil studies.

The understanding of why the heterogeneity is produced, and what the nature of such heterogeneity is, is a need under the scientific and practical points of view. Any coherent explanation on the origin of heterogeneity should help to understand it and to choose the adequate mathematical techniques for handling it with prediction purposes.

In this paper an extremely simple model is presented, which gives a consistent explanation of the complexity of spatial variability of chemicals or pollutants in soil shown in former studies.

The results shown here strongly suggest the use of scaling methods coming from fractal geometry for the study of this kind of distributions.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgment

This research work was funded by Spain’s Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica (I+D+I), under ref. AGL2011-25175.

References

  1. J. J. McDonnell, M. Sivapalan, K. Vaché et al., “Moving beyond heterogeneity and process complexity: a new vision for watershed hydrology,” Water Resources Research, vol. 43, Article ID W07301, 2007. View at Publisher · View at Google Scholar
  2. E. Montero, “Rényi dimensions analysis of soil particle-size distributions,” Ecological Modelling, vol. 182, no. 3-4, pp. 305–315, 2005. View at Publisher · View at Google Scholar · View at Scopus
  3. M. A. Martín and C. García-Gutiérrez, “Log selfsimilarity of continuous soil particle-size distributions estimated using random multiplicative cascades,” Clays & Clay Minerals, vol. 56, no. 3, pp. 389–395, 2008. View at Publisher · View at Google Scholar · View at Scopus
  4. U. Frisch and D. Sornette, “Extreme deviations and applications,” Journal de Physique I France, vol. 7, pp. 1155–1171, 1997. View at Google Scholar
  5. D. Sornette, Critical Phenomena in Natural Sciences. Chaos, Fractals, Self-organization and Disorder: Concepts and Tools, Springer Series in Synergetics, Springer, New York, NY, USA, 2000.
  6. M. A. Martín, C. García-Gutiérrez, and M. Reyes, “Modeling multifractal features of soil particle size distributions with Kolmogorov fragmentation algorithms,” Vadose Zone Journal, vol. 8, no. 1, pp. 202–208, 2009. View at Publisher · View at Google Scholar · View at Scopus
  7. A. N. Kravchenko, C. W. Boast, and D. G. Bullock, “Multifractal analysis of soil spatial variability,” Agronomy Journal, vol. 91, no. 6, pp. 1033–1041, 1999. View at Publisher · View at Google Scholar · View at Scopus
  8. J. Lehmann, D. Solomon, J. Kinyangi, L. Dathe, S. Wirick, and C. Jacobsen, “Spatial complexity of soil organic matter forms at nanometre scales,” Nature Geoscience, vol. 1, no. 4, pp. 238–242, 2008. View at Publisher · View at Google Scholar · View at Scopus
  9. I. Rodríguez-Iturbe and A. Rinaldo, Fractal River Basins: Chance and Self-Organization, Cambridge University Press, Cambridge, UK, 1997.
  10. C. E. Shannon, “A mathematical theory of communication,” The Bell System Technical Journal, vol. 27, pp. 379–423, 623–656, 1948. View at Publisher · View at Google Scholar · View at Zentralblatt MATH · View at MathSciNet
  11. A. I. Khinchin, Mathematical Foundation of Information Theory, Dover Publications, New York, NY, USA, 1957. View at MathSciNet
  12. A. A. Rényi, “Statistical decision functions and random processes,” in Proceedings of the 2nd Prague Conference on Information Theory, pp. 545–556, 1957.
  13. J. H. Elton, “An ergodic theorem for iterated maps,” Ergodic Theory and Dynamical Systems, vol. 7, no. 4, pp. 481–488, 1987. View at Publisher · View at Google Scholar · View at Zentralblatt MATH · View at MathSciNet