Research Article

A New Equation Relating the Viscosity Arrhenius Temperature and the Activation Energy for Some Newtonian Classical Solvents

Table 1

Arrhenius parameters of some pure liquids studied at previous works, Arrhenius activation energy (kJ·mol−1), the logarithm of the entropic factor of Arrhenius /Pa·s), the Arrhenius temperature (/K), Arrhenius activation temperature (/K), the melting point (/K), and the boiling point (/K).

NumberPure componentReference/K/kJ·mol−1/K/K/K

1Acetone[11]894.9−11.0977.440680.643329.20178.45
2Acetic acid[11]1348.6−11.30811.213119.26391.15289.75
3Aniline[11]2405.1−13.56419.997177.32457.28266.85
4Butyl alcohol[11]2298.9−13.68919.114167.94390.85183.35
5Carbone tetrachloride[11]1242.3−11.15210.329111.39349.87250.23
6Ethyl acetate[11]1192.9−11.7289.9183101.72350.15189.55
7Diethyl ether[11]904.48−11.4467.520379.021307.75156.85
8n-Heptane[11]1036.7−11.3028.619691.723371.15182.55
9n-Pentane[11]733.64−10.8866.099867.393309.25143.45
10Toluene[11]1085.2−11.1359.022997.461383.75180.15
11m-Xylene[11]1052.2−10.9758.748595.872412.25225.35
12n-Octanol[45]3001.4−14.94524.955200.83468.15257.15
13Propylene glycol[46]5744.8−22.12847.765259.62461.35214.15
14Butane-1,2-diol[47]5281.1−20.68143.910255.36465.15159.15
15Butane-1,4-diol[47]4012.2−16.21033.359247.51503.15293.15
16Propylene glycol[48]4516.3−18.26637.551247.25461.35214.15
171,2-Butanediol[48]5624.3−21.85746.763257.32465.15159.15
181,2-Butanediol[48]5524.5−21.51045.933256.84465.15159.15
191,4-Butanediol[48]4093.3−16.48534.033248.31503.15293.15
201,4-Butanediol[48]4077.7−16.43833.904248.07503.15293.15
21Benzene[11]1315.8−11.81210.940111.39353.15278.65
22Chlorobenzene[11]1047.5−10.6958.709497.939405.15228.15
23Ethylbenzene[11]1095.8−11.0279.111099.375409.15178.15
24o-Xylene[11]1183.0−11.1459.8360106.14417.15248.65
25N,N-Dimethylacetamide[49]1173.7−10.9149.7590107.54438.55253.15
26Formamide[49]1973.7−12.44216.410158.63483.15275.65
27N,N-Dimethylformamide[49]1088.8−10.7809.0530101.00425.00212.15
28N,N-Dimethylacetamide[50]1133.7−10.8969.4260104.05438.55253.15
29Water[50]1865.4−13.28415.510140.42373.15273.15
302-Methoxyethanol[50]1826.3−12.60215.185144.93397.65188.15
31N,N-Dimethylacetamide[51]1178.3−10.9349.7973107.77438.55253.15
322-Ethoxyethanol[51]1900.7−12.68215.803149.87408.15183.15
33Water[52]1914.7−13.44315.920142.43373.15273.15
341,4-Dioxane[52]1522.6−11.85312.660128.47374.15284.15
35Water[53]1894.2−13.38315.749141.54373.15273.15
36Isobutyric acid[53]1338.1−11.20011.126119.48426.65226.15
37Water[54]1856.2−13.23215.433140.28373.15273.15
38Ethanol[54]1588.1−12.16613.204130.50351.15159.15
39Water[55]1881.1−13.33415.640141.07373.15273.15
40Methanol[55]1194.8−11.5289.9340103.64337.75175.55
41Dimethylsulfoxide[56]1690.8−11.87214.058142.42462.15290.65
42p-Xylene[56]1009.3−10.7618.392093.800411.15285.65
43Dimethylsulfoxide[57]1723.9−12.00214.333143.63462.15290.65
44o-Xylene[57]1151.4−11.0449.5730104.26417.15248.65
45Water[58]2006.6−13.74216.684146.02373.15273.15
461,4-Dioxane[58]1403.5−11.43011.669122.78374.15284.15
47Ethylene glycol[58]3601.1−16.14629.941223.03470.15260.15
48Triethyl amine[59]987.68−11.2488.212087.810361.95158.15
49Water[60]1898.6−13.38915.786141.80373.15273.15
50Glycerol[61]7169.2−24.14359.608296.95455.15293.15
51TEGMME[62]2555.2−13.63821.245187.36395.15229.15
52n-Heptane[63]1725.2−12.61314.344136.78371.15182.15
531-Propanol[64]2139.9−13.41517.792159.51370.15149.15
542-Propanol[64]2640.0−15.03221.950175.63355.15183.65
55t-Butanol[64]3852.2−18.47632.029208.50355.55298.84
56Allyl alcohol[64]1840.8−12.86615.305143.07370.15144.15
57Propargyl alcohol[64]1816.7−12.60715.105144.10387.65220.15
58Dimethylsulfoxide[65]1409.7−10.97511.721128.44462.15290.65
59Benzene[65]1798.7−13.25414.955135.71353.15278.65
60Ethylbenzene[65]1022.5−10.8078.501694.617409.15178.15
61Chlorobenzene[65]954.13−10.4067.933191.687405.15228.15
62Bromobenzene[65]2017.1−13.45016.771149.98429.15242.15
631,4-Dioxane[66]1452.2−11.60712.074125.11374.15284.15
64Ethanol[66]1885.9−12.99715.680145.10351.15159.15
652-Propanol[66]3058.5−16.40325.430186.46355.15183.65
66Isoamyl alcohol[66]2602.7−14.32221.640181.72403.15156.15
673-Amino-1-propanol[66]4336.9−18.03636.059240.46458.65284.15
68Water[67]1872.4−13.30715.568140.70373.15273.15
692-Methoxyethanol[67]1744.4−12.66214.504137.77397.65188.15
70N-Methylacetamide[67]2300.6−13.15519.128174.88478.15300.15
71Propylene carbonate[68]1706.9−11.72914.192145.53513.15218.15
721,2-Diethoxyethane[69]910.34−10.8197.569084.142394.15199.15
73Acetonitrile[70]840.64−10.7936.989577.885354.65222.15
74Methanol[71]1226.5−11.62910.198105.47337.75175.55
75Tetrahydrofuran[71]810.42−10.3936.738277.977339.15165.15

TEGMME is an abbreviation of triethylene glycol monomethyl ether.