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Journal of Chemistry
Volume 2015, Article ID 540368, 13 pages
Research Article

An Exact Method to Determine the Conductivity of Aqueous Solutions in Acid-Base Titrations

1Laboratorio R-105/R-107, Área de Química Analítica, Departamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa, Avenida San Rafael Atlixco 186, Colonia Vicentina, 09340 México, DF, Mexico
2Área Ingeniería de Materiales, Departamento de Materiales, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Azcapotzalco, Avenida San Pablo 180, Colonia Reynosa-Tamaulipas, 02200 México, DF, Mexico

Received 6 November 2014; Accepted 8 January 2015

Academic Editor: Patricia Valentao

Copyright © 2015 Norma Rodríguez-Laguna et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. I. N. Levine, Fisicoquímica, vol. 2, McGraw-Hill, Madrid, Spain, 5th edition, 2004.
  2. A. J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications, John Wiley & Sons, New York, NY, USA, 1980.
  3. C. J. M. Pingarrón, Química Electroanalítica. Fundamentos y Aplicaciones, Síntesis, Madrid, Spain, 2003.
  4. J. A. Dean, “Electrolytes, electromotive force, and chemical equilibrium,” in Lange's Handbook of Chemistry, p. 8.113, McGraw-Hill, New York, NY, USA, 1999. View at Google Scholar
  5. J. Hen, “Determination of surface carboxyl groups in styrene/itaconic acid copolymer latexes,” Journal of Colloid and Interface Science, vol. 49, no. 3, pp. 425–432, 1974. View at Publisher · View at Google Scholar
  6. P. Brunatti and H. De Nápoli, “Titulaciones Conductimétricas,” 2014,
  7. J. Darias-Martín, A. Socas-Hernández, and C. Díaz-Romero, “Comparative study of methods for determination of titrable acidity in wine,” Journal of Food Composition and Analysis, vol. 16, no. 5, pp. 555–562, 2003. View at Publisher · View at Google Scholar · View at Scopus
  8. G. M. Fleck, Equilibrios en Disolución, Alhambra, Madrid, Spain, 1967.
  9. P. Tarapčik and E. Beinrohr, Implementation of a Universal Algorithm for pH Calculation into Spreadsheet and Its Use in Teaching in Analytical Chemistry, Faculty of Chemical and Food Technology STU, Bratislava, Slovakia, 2005.
  10. R. de Levie, “General expressions for acid-base titrations of arbitrary mixtures,” Analytical Chemistry, vol. 68, no. 4, pp. 585–590, 1996. View at Publisher · View at Google Scholar
  11. R. Gutz,
  12. C. E. Efstathiou, 2014,
  13. A. G. Asuero and T. Michalowski, “Comprehensive formulation of titration curves for complex acid-base systems and its analytical implications,” Critical Reviews in Analytical Chemistry, vol. 41, no. 2, pp. 151–187, 2011. View at Publisher · View at Google Scholar · View at Scopus
  14. A. Rojas-Hernández, N. Rodríguez-Laguna, M. T. Ramírez-Silva, and R. Moya-Hernández, “Distribution diagrams and graphical methods to determine or to use the stoichiometric coefficients of acid-base and complexation reactions,” in Stoichiometry and Research—The Importance of Quantity in Biomedicine, A. Innocenti, Ed., chapter 13, pp. 287–310, InTech, Rijeka, Croatia, 2012. View at Publisher · View at Google Scholar
  15. N. Rodríguez-Laguna, A. Rojas-Hernández, and M. T. Ramírez-Silva, “Study and behavior of the buffer capacity of mixtures of species of a same protons poly-donor system,” Educacion Quimica, vol. 25, no. 1, pp. 210–222, 2014 (Spanish). View at Google Scholar · View at Scopus
  16. A. Rojas-Hernández, M. T. Ramírez-Silva, A. Galano, J. L. Córdova Frunz, and J. F. Pérez Arévalo, “Charlot’s equation, and flood and gordus graphs,” Educación química, vol. 21, no. 4, pp. 306–313, 2010 (Spanish). View at Google Scholar
  17. N. Rodríguez-Laguna, Theoretical contributions to the buffer capacity notion considering insoluble and polynuclear species [Ph.D. thesis], Universidad Autónoma Metropolitana-Iztapalapa, Mexico City, Mexico, 2015, (Spanish).
  18. D. C. Harris, Análisis Químico Cuantiativo, Reverté, Barcelona, Spain, 3rd edition, 2003.
  19. J. M. Islas-Martínez, D. Rodríguez-Barrientos, A. Galano et al., “Deprotonation mechanism of new antihypertensive piperidinylmethylphenols: a Combined Experimental and Theoretical Study,” Journal of Physical Chemistry B, vol. 113, no. 34, pp. 11765–11774, 2009. View at Publisher · View at Google Scholar · View at Scopus
  20. I. Puigdomenech, Making Equilibrium Diagrams Using Sophisticated Algorithms (MEDUSA), 2014,