Journal of Chemistry

Journal of Chemistry / 2015 / Article

Research Article | Open Access

Volume 2015 |Article ID 620938 | https://doi.org/10.1155/2015/620938

Álvaro Fontana, Fábio Santana dos Santos, Flávia Aparecida Fonseca, Adonilson Dos Reis Freitas, Andersson Barison, Jarem Raul Garcia, "Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization", Journal of Chemistry, vol. 2015, Article ID 620938, 8 pages, 2015. https://doi.org/10.1155/2015/620938

Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization

Academic Editor: Ewa Schab-Balcerzak
Received06 Feb 2015
Revised12 Apr 2015
Accepted16 Apr 2015
Published10 May 2015

Abstract

Organic synthesis of the monomer of poly(p-phenylenevinylene) was performed starting by the 2,5-dimethylphenol compound. An iodine atom was added to one end of the aromatic ring and then the iodine atom was substituted by a cyano group. Opposite to the cyano group was added a chain of six carbon atoms and the end of the carbon chain has an added bromine atom. The characterizations of the obtained compounds were made by FTIR, GC-MS, 1H, and 13C NMR and showed that almost all of the proposed monomers were obtained in their totality.

1. Introduction

One of the ways used to change the electronic properties of conjugated polymers is to add side chain substituents, donors, and/or electron acceptors in the polymer chain, as it is known that when substituted benzenes undergo electrophilic attack, the substituent groups already present in the ring affect the rate of reaction and the attack site. The substituent groups can be divided into two classes according to their influence on the reactivity of the ring [14].

Those which make ring more reactive than benzene are activator groups, and those which make the ring less reactive than benzene are called deactivator groups. The activating groups on the aromatic ring influence electrophilic reactions in order to guide the attack electrophiles in a position ortho or para to the substituent of the ring, which may also be called guiding ortho-para. In other classes of substituents, the deactivator tends to direct electrophilic substitution at the meta position, so we call this groups of guiding meta. In the case of the monomer to be prepared in this study, the starting material 2,5-dimethylphenol has a hydroxyl group, and this group directs all reactions carried out in the ortho and para positions, being an activator group, or makes them more reactive aromatic ring due to partial increase of negative charges in the ortho and para positions [4].

Two effects are responsible for the orientations of the aromatic electrophilic substitutions: inductive effect and the resonance effect. The resonance effect, that is, the effect realized by hydroxyl present in the 2,5-dimethylphenol, is found by substituents which have one or more pairs of nonbonding electrons and refers to the ability to increase or decrease the stability of intermediate ion by resonance [47]. The substituent group can, for example, cause one of the contributions to the resonance hybrid. As for activating groups, they are those that increase the stability of the ring by injecting electrons into the aromatic ring. The effect is illustrated in Scheme 1.

By carefully choosing the deactivator or activating group or altering the side chain functionalities, one should be able to fabricate polymeric films to be applied as an active layer of electrochemical sensors, for example, humidity sensors [3].

In this paper we propose the synthesis of a derivative monomer PPV that has in its structure a cyano group and π-acceptor, connected directly to the ring, since it is known that this group stabilizes the HOMO and LUMO levels, being able to control their relatives positions [8]. In the para position to the cyano group we introduce a six carbon atoms chain and at the end of the carbon chain there is a bromine atom.

2. Materials and Methods

2.1. Synthesis of 4-Iodo-2,5-dimethylphenol

In this organic synthesis, Scheme 2, we used 0.02 moles of 2,5-dimethylphenol and equivalent amounts of sodium iodide and sodium hydroxide were dissolved in 50 mL of methanol present in a three-necked flask. The solution was cooled in an ice bath and sodium chloride solution until the temperature reached 0°C for temperature control coupled to a thermometer in one of the necked flasks. In another necked flask adapted to an addition funnel containing 37.5 mL of a sodium hypochlorite solution at 4% w/w. This solution was slowly dripped into the solution contained in the flask in a way that the temperature did not exceed 4°C.

The mixture was stirred with the aid of magnetic stirring and after the addition of all the solution from the funnel, the mixture was left under stirring for another two hours at a temperature between 0 and 2°C [9]. For product purification, the obtained solution was treated with 40 mL of an aqueous solution of sodium thiosulfate (Na2S2O3) to 10% and then the pH was adjusted to 7.0 using a 10% hydrochloric acid solution. In some cases the product was crystallized at this point and can thus be filtered. By having no crystallization occurred, 50 mL of chloroform was added and the phases were separated by separatory funnel. So it was added to the calcium carbonate anhydrous in the organic phase (drying agent) and the solution was then filtered and the solvent was subjected to fractional distillation under reduced pressure, b.p. about 40°C/400 mmHg [10]. The product, 4-iodo-2,5-dimethylphenol, had a yield of 75% and the melting point of the crystals was approximately 90°C.

2.2. Synthesis of 4-Hydroxy-2,5-dimethylbenzonitrile

In the synthesis of Scheme 3, 0.02 moles of 4-iodo-2,5-dimethylphenol obtained above was also employed and was dissolved in 20 mL of N, N-dimethylformamide (DMF) and the mixture brought to an addition funnel. An equivalent amount in moles plus 10% copper cyanide was also dissolved in 20 mL of DMF and added to a three-way flask [8, 9].

The system has been mounted in which a flask inputs received the dropping funnel; the other was connected to a condenser and the third way is closed. With the aid of magnetic stirrer and heater it started heating. With the beginning of reflux the entire solution was dripped slowly in the dropping funnel. After complete addition, the solution was refluxed continuously for another 6 hours [9]. After time of reflux, the solution was allowed to reach room temperature and was added to 40 mL of a saturated solution of ethylenediaminetetraacetic EDTA, which was allowed to stir for 24 hours.

After this stage, the solution was cooled down to obtain better crystals and then filtered. For purification the product was performed chemically active with an extraction solvent, where it is first dissolved in chloroform and we transferred the entire contents to a separating funnel, which underwent five washes with 5% sodium hydroxide. When obtaining an aqueous extract it was adjusted to pH 7.0 with drops of concentrated hydrochloric acid to obtain a precipitate which is filtered and dried in a vacuum desiccator [9, 11]. The product was obtained in a yield of 35%, and its melting point was 121°C.

2.3. Synthesis of 4-[(6-Hydroxyhexyl)oxy]-2,5-dimetilbenzonitrile

The synthesis of Scheme 4 followed the method described by Chang et al. [10], where compound was prepared by alkylation of 4-hydroxy-2,5-dimethylbenzonitrile with 6-chlorohexan-1-ol. A solution of 0.01 moles of 4-hydroxy-2,5-dimethylbenzonitrile, 0.015 moles of potassium hydroxide, and 0.00105 moles of tetrabutylammonium bromide in 20 mL of distilled water was stirred at room temperature for 15 minutes. Subsequently we slowly added 0.01 moles of 6-clorohexan-1-ol [10].

The reaction proceeded with stirring and reflux for 22 hours. After complete reaction the product was extracted with 30 mL of chloroform. This organic phase was washed with a sodium hydroxide solution of 10% and boiling water successively. Dry the resulting organic layer with anhydrous magnesium sulphate for 24 hours, and then we filtered and carried out a fractionated distillation of the solvent under reduced pressure, b.p. about 40°C/400 mmHg, to give 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile, a light brown oil [10, 12]. From the obtained mass, the volume was calculated using the approximate density of the compound, 1.33 gmL−1, and had a yield of about 30%.

2.4. Synthesis of 4-[(6-Bromohexyl)oxy]-2,5-dimetilbenzonitrile

For this synthesis, Scheme 5 was adapted from the hydrobromic acid’s method described by [13], where the procedure was applied for the preparation of 4-[(6-bromohexyl)oxy]-2,5-dimetilbenzonitrile from 4-[(6-hydroxyhexyl)oxy]-2,5-dimetilbenzonitrile. In a 25 mL flask 0.50 mL of concentrated sulphuric acid was slowly dissolved in 0.80 mL of 48% hydrobromic acid under stirring and external cooling. 1.5 mL of 4-[(6-hydroxyhexyl)oxy]-2,5-dimetilbenzonitrile was added then portion wise we added over 0.35 mL of concentrated sulphuric acid [12].

The system was allowed to warm to 30°C for 2 hours and formed two phases. We moved the cooled reaction mixture to a separatory funnel, separated the organic phase, washed it with 20 mL 10% hydrochloric acid, 20 mL of distilled water, and 10 mL of an aqueous solution of 5% sodium hydroxide, and finally we washed it again with 20 mL of distilled water. The dry organic phase was extracted with anhydrous magnesium sulphate during a time of 24 hours.

With filtration of the dried product directly to a 25 mL flask and held fractional distillation under reduced pressure, b.p. about 40°C/400 mmHg, the yield was approximately 85%.

In addition to the techniques FTIR and NMR this reaction was characterized by GC-MS to verify the change of the hydroxyl group by bromine.

The solid obtained was dissolved in appropriated solvent at room temperature. An appropriate solution volume was injected into the chromatographer with a microsyringe. GC-MS was performed in a Shimadzu gas chromatograph coupled with a mass selective detector model QP2000A.

A 60 m long and 0.25 mm diameter SE-30 GC capillary column coated with poly(dimethyl siloxane) was used and the appropriate solution was injected at 80°C. Column temperature was programmed to remain at 40°C for 6 min and then raised to 150°C at a heating rate of 10°C min−1. Helium was used as a carrier gas at a flow rate of 30 mL min−1.

3. Results and Discussion

3.1. Characterization of 4-Iodo-2,5-dimethylphenol

In the reaction described for obtaining 4-iodo-2,5-dimethylphenol, it is necessary basic medium to occur, NaOH, because the presence of the base has the function to remove a proton from the hydroxyl group present in the compound 2,5-dimethyl-phenol, thereby forming an activating group ortho-para more reactive than phenol, which makes entry iodine atom in the para position favorable with respect to the hydroxyl group. As to attack of the electrophilic compound, it is generated in situ in the reaction medium by the reaction of sodium iodide with sodium hypochlorite which causes the 3I/ complex to remain in its oxidized form, .

To precipitate the crystals, the pH was adjusted to 7 for the product to acquire the characteristic of the organic salt and thus lose the water solubility. We carried out measurement of the melting point and this was 90°C, while the theoretical melting point of this compound is between 94 and 95°C. Compared to the melting point of 2,5-dimethylphenol, 75°C, it appears that the increase in temperature recorded is consistent, given that the addition of an iodine atom increases the molecular weight of the compound thereby increasing its melting point.

The compound was characterized by infrared spectroscopy, FTIR, and nuclear magnetic resonance 1H NMR, and such characterizations are shown in Figures 1 and 2, respectively.

In Table 1 some major bands found in the infrared spectrum obtained in KBr tablet are shown.


Chemical bondStretchAbsorption band (cm−1)

O-HAxial deformation3340
C-H Csp3 methylAxial deformation2914–2857
C=C aromatic ringAxial deformation 1543, 1406 and 1250
C-OAxial deformation1134
C-IVibration602

The characterization by 1H NMR to ascertain main reason is that the connection of the ring formed with iodine is carried out in carbon position to the radical present in the phenol ring.

The 1H NMR spectrum of Figure 2 was obtained in CDCl3 solvent, peak at 7.25 ppm. The peaks found in δ~4.67 ppm and δ~1.63 ppm can be hydrogen from hydroxyl group and water dissolved in chloroform, respectively, in the sample, because in solvent we used traces of water that may be contaminating the sample show peaks in these values [13, 14]. Another possibility is that the hydrogen atom behavior of hydroxyl phenols resembles the hydrogen atom of the hydroxyl alcohols. The corresponding signal is usually a sharp singlet (fast change without coupling), and the region that appears depends on the compound concentration, of the solvent and temperature, being generally in the left (δ~7.5 to δ~4.0 ppm) of hydrogen atom sign of hydroxyl of alcohol. Signals at 6.69 and 7.52 ppm correspond to protons of aromatic ring and signals at 2.32 and 2.17 ppm correspond to methyls groups to the aromatic ring [15].

The result showed that the product obtained was really the 4-iodo-2,5-dimethylphenol. The yield of synthesis was about 70%. One possible alternative for increasing the yield of this reaction was dripped sodium hypochlorite more slowly to the reaction mixture or to control the temperature so that it does not exceed 2°C [16].

3.2. Characterization of 4-Hydroxy-2,5-dimethylbenzonitrile

The inclusion of the cyanide group, π-acceptor group of electrons, stabilizes energy levels HOMO and LUMO by changing the electronic distribution of the molecule. But the entry of cyanide group in the aromatic ring does not occur easily as the halogens. Therefore it was necessary to have a good leaving group in the ring for the later entrance of the cyanide group. Then first iodine atom was added in 2,5-dimethylphenol compound, being a good leaving group, for later reaction with cyanide group.

The theoretical melting point of this compound is 110°C. The melting point of the compound is consistent when comparing it with the 2,5-dimethylphenol, 75°C, and the 4-iodo-2,5-dimethylphenol, 90°C, since the addition of a CN group increases the number of hydrogen bonds by increasing the intermolecular force system which causes the melting point to be also higher. To verify the formation of CN-C coupling was performed and FTIR spectroscopy, obtaining the spectrum of Figure 3.

The assignment of the bands observed in this spectrum can follow the same system used in the allocation of spectrum bands of 4-hydroxy-2,5-dimethylbenzonitrile. However one must consider the disappearance of the band at 602 cm−1 shown in Figure 1 related to the axial vibration of the C-I bond and the appearance of the band at 2224 cm−1 in Figure 3 which can be attributed to the presence of the CN group.

In Table 2 some major bands found in the infrared spectrum obtained in KBr tablet are shown.


Chemical bondStretchAbsorption band (cm−1)

O-HAxial deformation3332
C-H Csp3 methylAxial deformation2922–2857
CNAxial deformation2224
C=C aromatic ringAxial deformation1543, 1406 and 1250
C-OAxial deformation1134

The 1H NMR spectrum in Figure 4 was obtained using CDCl3 solvent, peak at 7.25 ppm, and showed other peaks.

In the spectrum of Figure 4 a peak was also observed at 3.63 ppm which can be hydrogen of hydroxyl group and at 1.15 ppm which can indicate that the sample is possibly contaminated with traces of water, while making the purification process as described in [17]. Shifting the two signals seen in Figure 4 (3.63 and 1.15 ppm) in relation to Figure 3 may be attributed to the electronic effects of the CN group in the molecule [1, 4, 9, 11].

Peaks found in the 1H NMR showed the chemical shifts expected for the hydrogen atoms present in the molecule 4-hydroxy-2,5-dimethylbenzonitrile. With the results obtained by the characterizations, we confirmed the formation of the expected product in this organic synthesis.

3.3. Characterization of 4-[(6-Hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile

This reaction aims to form a compound containing six carbon atoms between the aromatic ring and an OH grouping at end of chain. This structure is interesting to act as a strong flexible drive to the proton conduction function in the compound after the polymerization [14].

According to the spectrum shown in Figure 5, the bands found correspond to the compound 4-[(6-hydroxyhexyl)oxy]-2,5-dimetilbenzonitrile. It was confirmed that the existence of the spectrum CN group of methyl bound to the aromatic ring of the side chain methylene present in the compound and that the presence of the alcoholic, OH group and ether was attached to the aromatic ring.

The values of the bands of each connection are shown in Table 3. To confirm obtaining the compound, 1H NMR analyses, Figure 6, were performed in order to compare product formation by the existence of a CN group bound to the aromatic ring and the existence of the chain side containing six carbon atoms having the OH group at the end of the carbon chain.


Chemical bondStretchAbsorption band (cm−1)

O-HAxial deformation3400
C-H Csp3 methylAxial deformation2940
C-H Csp3 (-CH2-) Axial deformation (asymmetric and symmetric)2853
CNAxial deformation2220
C=C aromatic ringAxial deformation1600, 1500
C-O (alkyl-aryl-ether)Axial deformation (asymmetric and symmetric)1250
C-O alcoholAxial deformation1080

The spectrum of Figure 6 was obtained in CDCl3 solvent, peak at 7.25, and shows two singlets relating to the chemical shift region of hydrogen atom attached to the aromatic ring in 7.30 and 6.65 ppm. These peaks indicate that only two singlets of the aromatic ring carbons are not substituted and hydrogen atoms are not close to each other. The region between the peaks of 1.45 and 1.82 ppm are indicative of protons belonging to the side chain. The peak in 3.97 ppm can be traces of water and the peak in 3.65 ppm is signal with respect to proton linked to ether group in molecule.

It can be said then that the aromatic ring is connected to not only the methyl group in positions 2 and 5 because of the signs in 2.47 and 2.15 ppm, but also the cyano group and the side chain composed of 6 carbon atoms attached to the aromatic ring and a hydroxyl group at the end of carbon chain.

3.4. Characterization of 4-[(6-Bromohexyl)oxy]-2,5-dymethylbenzonitrile

According to Figure 7, it is not possible to say with certainty whether there was formation of compound 4-[(6-bromohexyl)oxy]-2,5-dimethylbenzonitrile, since the difference between the this compound and 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile is the carbon-bromine bond in the end of the side chain where the hydroxyl group was replaced by a bromine atom. The bromine compound absorbs in the regions of 690 and 515 cm−1 and in Figure 7 there are two very close bands with these theoretical values for the bromination reaction of halogenated organic compounds signs but they have lower intensity than expected.

It is also possible to see that there was a decrease of the band at 3470 cm−1 when compared to the spectrum of Figure 5 which corresponds to compound 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile, in that region, indicating the presence of hydroxyl group at the end of the chain. It might be supposed that there is substitution of the hydroxyl group by a bromine atom at the end of the side chain; however, bands corresponding to bromine absorption are small. To confirm the structure of the compound 1H NMR analysis was done as it can be seen in Figure 8.

Figure 8 shows that the 1H NMR spectrum of the compound 4-[(6-bromohexyl)oxy]-2,5-dimethylbenzonitrile was obtained in CDCl3 solvent, which is the difference in molecular structure compared to the compound 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile of Figure 6, which is bromine-carbon bond at one end of the side chain in place of the hydroxyl group.

In Figure 8 a signal appears at 3.65 ppm; it is signal with respect to proton linked to ether group in molecule and has a triplet at 3.41, but with lower intensity. The region between the peaks of 1.42 and 1.81 ppm is indicative of protons belonging to the side chain. The remainder of the observed signals is quite similar for both compounds. To confirm if they were actually replacing the hydroxyl group by a bromine atom in the compound 4-[(6-hydroxyhexyl)oxy]-2,5-dimetilbenzonitrile 13C NMR analysis was made as shown in Figure 9.

The chemical shifts of the signal expected for the carbon-bromine bond are at 33.80 ppm, whereas carbon-hydroxyl bond happens at 62.70 ppm. There is a chemical shift signal at 32.79 ppm and a small signal at 33.60 ppm. These values could be evidence that the compound 4-[(6-bromohexyl)oxy]-2,5-dimethylbenzonitrile was obtained but in the same spectrum there is a signal at 62.93 ppm. These values lead us to believe that the compound was obtained but is present in a mixture with the 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile compound.

In Figure 10 the multiple peaks in the GC-MS chromatogram reveal that several products are formed during a synthesis process. Freitas et al. [17] used this technique in available degradation process of polychloroprene. He measured the appearing new peaks in CG-MS as functioning as degradation reaction. Curti et al. [18] study of similar system arrived at same conclusion. This technique permits availing the appearing or disappearing, such as the identification of substance in a chemical process. In this sense, the GC-MS was used. In this spectrum it is possible to see the presence of duplicate signal of the molecular ion bromine isotope in = 308.98 and the peak signal based on = 147 which is expected to sign the most stable fragment, C9H8ON.

Due to large extension of the target molecule an enormous fragment was waited in chromatogram. Peak with = 310 was found, C15H20BrON. These peaks found in the chromatogram are according to data from NMR and FTIR spectroscopy and this permits us to conclude that target molecule was obtained.

4. Conclusion

In this work organic synthesis of the monomers precursors of class of the poly-p-phenylenevinylene for possible later electropolymerization was made, whose infrared spectra are 1H and 13C. NMR data confirmed obtaining the compounds, 4-iodo-2,5-dimethylphenol, 4-hydroxy-2,5-dimethylbenzonitrile, and 4-[(6-hydroxyhexyl)oxy]-2,5-dimethylbenzonitrile, wherein the compound 4-[(6-bromohexyl)oxy]-2,5-dimethylbenzoni-trile was obtained but contains impurities in its structure, or associated to a mixture of compounds; this result is also confirmed by Figure 10, GC-MS technique, and Figure 9, 13C NMR spectrum.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

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Copyright © 2015 Álvaro Fontana et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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