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Journal of Chemistry
Volume 2015 (2015), Article ID 876821, 17 pages
Review Article

A Comprehensive Review on Measurement and Correlation Development of Capillary Pressure for Two-Phase Modeling of Proton Exchange Membrane Fuel Cells

1State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206, China
2Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy, North China Electric Power University, Beijing 102206, China
3Department of Energy and Refrigerating Air-Conditioning Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
4Mathematics and Physics Department, North China Electric Power University, Beijing 102206, China

Received 21 October 2014; Revised 23 March 2015; Accepted 24 March 2015

Academic Editor: Tingyue Gu

Copyright © 2015 Chao Si et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Water transport and the corresponding water management strategy in proton exchange membrane (PEM) fuel cells are quite critical for the improvement of the cell performance. Accuracy modeling of water transport in porous electrodes strongly depends on the appropriate constitutive relationship for capillary pressure which is referred to as - correlation, where is the capillary pressure and is the fraction of saturation in the pores. In the present PEM fuel cell two-phase models, the Leverett-Udell - correlation is widely utilized which is proposed based on fitting the experimental data for packed sands. However, the size and structure of pores for the commercial porous electrodes used in PEM fuel cells differ from those for the packed sands significantly. As a result, the Leverett-Udell correlation should be improper to characterize the two-phase transport in the porous electrodes. In the recent decade, many efforts were devoted to measuring the capillary pressure data and developing new - correlations. The objective of this review is to review the most significant developments in recent years concerning the capillary pressure measurements and the developed - correlations. It is expected that this review will be beneficial to develop the improved PEM fuel cell two-phase model.