Research Article

Synthesis and Characterization of Chloridobis(dimethylglyoximato)4-(2-ferrocenylvinyl)pyridinecobalt(III): A New Heterobinuclear Cobaloxime

Table 1

Spectroscopic and electrochemical properties of 4-(2-ferrocenylvinyl)pyridine, fcvpy, and .

  /fc (V versus Ag/AgCl) Co(III/II) (V versus Ag/AgCl) Co(II/I) (V versus Ag/AgCl)

Ferrocene4200.41
fcvpy310, 4600.48
255−0.64−1.03
334, 5050.58−0.54−1.02

Ferrocene and are included as reference. Measured in CH3CN solution.