Research Article

Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

Table 5

Comparison of oxidation of various organic substrates by TMGCC, TMGFC, PCC, PFC, BAAOC, and DmpzHFC.

Yield% (time [min])
SubstrateTMGCCTMGFCCPCC [20]PFC [31, 32]BAAOC [33]DmpzHFC [34]

4-Methoxybenzyl alcohol91 (1)90 (1)94 (5)89 (10)99 (2)92 (2)
4-Chlorobenzyl alcohol85 (1.5)86 (1)93 (10)78 (10)95 (7)ā€”
Benzyl alcohol85 (1)90 (0.5)96 (15)93 (10)98 (1)85 (1)
Cinnamyl alcohol85 (1)85 (0.5)95 (15)85 (10)85 (20)89 (2)