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Journal of Chemistry
Volume 2016 (2016), Article ID 5175746, 7 pages
http://dx.doi.org/10.1155/2016/5175746
Research Article

Extraction of Sodium Picrate by 3m-Crown-m Ethers and Their Monobenzo Derivatives (m = 5, 6) into Benzene: Estimation of Their Equilibrium-Potential Differences at the Less-Polar Diluent/Water Interface by an Extraction Method

Graduate School of Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Received 11 December 2015; Revised 1 March 2016; Accepted 8 March 2016

Academic Editor: Mostafa Khajeh

Copyright © 2016 Yoshihiro Kudo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Individual distribution constants () of picrate ion (Pic) and extraction constants () of NaPic by some crown ethers (L) into benzene (Bz) at 25°C were calculated from data reported previously. These constants were defined as and , respectively. Here, the subscript “o” denotes an organic (o) phase and practically o = Bz. 15-Crown-5 ether (15C5), 18-crown-6 one (18C6), and their monobenzo (B) derivatives (B15C5 and B18C6) were selected as L. Interfacial equilibrium-potential differences () at extraction were estimated at 298 K. A plot of versus for the four L extraction systems gave a straight line with slope = 84 V−1. This slope was compared with those, reported before, of the dichloromethane (DCM), 1,2-dichloroethane (DCE), and nitrobenzene (NB) extraction systems. The slopes of the regression lines were in the order NB < DCM ≤ DCE < Bz. Also, the individual distribution constants of the complex ion and an ion-pair complex () into Bz phase were calculated from the above extraction data. At least, a comparison between these values suggests that Bz molecules mainly interact with moiety of .