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Journal of Chemistry
Volume 2017 (2017), Article ID 7623210, 7 pages
https://doi.org/10.1155/2017/7623210
Research Article

Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand

1Laboratorio de Investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Química, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, Toluca, MEX, Mexico
2Centro de Química, ICUAP, Benemérita Universidad Autónoma de Puebla, CU, 72570 Puebla, PUE, Mexico
3Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón esq. Paseo Tollocan s/n, 50120 Toluca, MEX, Mexico
4Instituto de Química, Universidad Nacional Autónoma de México, Circuito Interior, Ciudad Universitaria, Coyoacán, 01450 Mexico City, Mexico

Correspondence should be addressed to Ivan GarcĂ­a-Orozco; xm.xemeau@oaicragi

Received 31 May 2017; Revised 11 September 2017; Accepted 14 September 2017; Published 30 October 2017

Academic Editor: Henryk Kozlowski

Copyright © 2017 Ricardo Rosas-Reyes et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Bis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S]nickel(II) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (CPDT) and Ni(II), and catena-[(μ2-4,4′-Bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S)]nickel(ΙΙ) 2 was prepared in good yields from 1 plus 4,4′-bipyridyl (bpy) by shish-kebab methodology. The structure of 1 was confirmed by FTIR, elemental analysis, 1H NMR, UV–vis in chloroform solution and in solid, XPS, and PXRD. Compound 2 was characterized by FTIR, elemental analysis, UV–vis in chloroform solution, and in solid, XPS, PXRD, ESR, and solid state magnetization measurements. The structure of the polymer was established mostly by PXRD, ESR, and magnetization.