Research Article
Molecular Encapsulation of Herbicide Terbuthylazine in Native and Modified β-Cyclodextrin
Table 3
1H NMR chemical shift (
δ) data of TBA, HP-
β-CD, and TBA/HP-
β-CD complex (see Scheme
2).
| H assignment | δ TBA (CD3OD/CDCl3) | δ HP-β-CD (CD3OD/CDCl3) | δ TBA/HP-β-CD (CD3OD/CDCl3) | Δδ |
| CH2 | 3.400 | — | 3.445 | 0.045 | t-Butyl | 1.426 | — | 1.430 | 0.004 | CH3 | 1.192 | — | 1.150 | −0.042 | H1′ | — | 5.099 | 5.097 | −0.002 | H3′ | — | 3.974 | 3.963 | −0.011 | H5′ | — | 3.830 | 3.821 | −0.009 | H6′ | — | 3.757 | 3.757 | 0.000 | H2′ | — | 3.520 | 3.521 | 0.001 | H4′ | — | 3.416 | 3.416 | 0.000 | CH3′ | — | 1.126 | 1.126 | 0.000 |
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