Abstract
Microwave pyrolysis is a potential for producing alternative fuel from biomass, such as palm kernel shell (PKS). However, the resulting microwave pyrolytic oil (bio-oil) was highly acidic and has low calorific value and therefore must undergo additional process to improve the physicochemical properties. In this study, attempt was made to improve the pH and calorific value of bio-oil produced from PKS via esterification process. The effect of esterification with ethanol in the presence of sulphuric acid as a catalyst on selected biodiesel qualities was also investigated. The esterification process has successfully improved the pH value from 3.37 to 5.09–5.12 and the calorific value was increased from 27.19 to 34.78–41.52 MJ/kg. Conclusively, the EO has comparatively better properties in terms of its smell, pH, calorific value, and absence of environmentally undesirable compounds. However, future works should include ASTM 6751 specifications tests for biodiesel to evaluate the bio-oil’s suitability for commercial use.
1. Introduction
Palm kernel shell (PKS) is a highly abundant waste generated from palm oil industry with high volatile matter content. PKS can be converted into renewable energy sources when subjected to suitable treatment such as microwave pyrolysis. In pyrolysis process, the biomass undergoes thermal decomposition in an oxygen-free environment to produce liquid, carbon-rich solid residue, and gases fuels synchronously.
In traditional pyrolysis, the system was performed using fixed bed, fluidized bed, circulating fluidized bed, and powder-particle fluidized bed, in which samples are heated externally using electrical heating [1]. Conventional heating has certain limitations such as heat transfer resistance, heat losses to surrounding, utilization of portion of heat supplied to biomass materials, and damage to reactor walls due to continuous electric heating [2]. Moreover, long heating period causes negative reactions in an undesirable or secondary reaction.
In the past decade, pyrolysis of biomass under microwave radiation has gained a lot of attention due to its advantages. During microwave pyrolysis, the microwave energy is accumulated precisely inside the material which creates spontaneous heat [3]. Microwave heating has been practiced to numerous kinds of biomass pyrolysis such as coal [4], oil shales [5], plastic wastes [6], sewage sludge [7, 8], wood block [9], corn stover [10], coffee hulls [11], rice straw [3], and pine sawdust [12].
In conventional heating, the heat is transported into the material through transmission, conduction, and radiation of heat from the surface of the material. In contrast, microwave energy is distributed straight into materials through molecular synergy with the electromagnetic field, thus obtaining a more uniform circulation of heat correlated with conventional heating [3, 10]. Uniform circulation of heat enables a well-controlled temperature adjustment and hence improved the process and the desired end products [10]. In addition, microwave heating contributes to volumetric heating mechanism at enhanced heating capability which saves energy compared to conventional systems [13].
In the sense of bio-oil production, microwave pyrolysis has been reported to prevent the chemical changes of volatiles product, thus attributed to better yield of bio-oil with low polycyclic aromatic hydrocarbons (PAHs) examined with those bio-oil obtained from conventional electrical furnace [7]. A study on microwave pyrolysis of rice straw also reported that the bio-oil product was highly alkylated and oxygenated and has less hazardous PAHs content [3]. However, significant concentrations of PAHs in bio-oil were reported when the input power of microwave was increased from 300 to 900 W [10].
Similar to other studies, microwave bio-oil has undesirable characteristics such as exalted viscosity, deficient heating rate, corrosiveness, and low resistance [14]. These properties will cause problems for direct use by engines. The microwave bio-oil is also highly acidic and has low calorific value and therefore must undergo additional process to improve the physicochemical properties. Esterification is a potential route to convert carboxylic acid in the bio-oil into ester by reacting them with alcohol, to improve the viscosity, corrosivity, calorific value, and chemical stability of the bio-oil as a fuel [14–16]. Thus, in this study, attempt was made to improve the pH and calorific value of bio-oil produced from PKS via esterification process.
2. Experimental
2.1. Materials
2.2. Experimental Setup
The experiments were carried out by setting samples in a quartz reactor and putting them inside the microwave. The quartz reactor was constructed using 15 mm inner diameter of gas inlet and outlet. Nitrogen gas was used to create an inert atmosphere in the reactor. A flow rate meter was used to control the gas purging into the reactor. The gas outlet was fastened to a condenser with tap water as a cooling condition.
2.3. Esterification of Bio-Oil
The esterification was performed by reacting PKO (1 g) with ethanol in the presence of sulphuric acid (as a catalyst). The esterification parameters are shown in Table 1. The molar ratio of ethanol to bio-oil was 1 : 1, 2 : 1, and 3 : 1 in 2 wt% of homogeneous catalyst. The mixture was refluxed for 60 and 120 minutes. A molecular sieve was used as a desiccant to remove water of reaction. The mixture was poured into a separating funnel containing 20 mL water. The flask was rinsed with diethyl ether (20 mL) and transferred into the separating funnel. The water layer was drained off and the ether layer was washed with water (20 mL) and 5% sodium bicarbonate. Saturated sodium chloride solution was added to the ether layer and freed from moisture by using anhydrous sodium sulphate and concentrated using a rotary evaporator. The esterified bio-oil (EO) was characterized using GC-MS. The EO was further characterized for its physical properties.
The CV of EO was analysed. The pH of the EO was measured using a pH meter from Eutech Instrument, type of pH 5/10. The EO density was determined using measuring cylinder and analytical balance. The EO was also analysed using FTIR spectrometer (Model: PerkinElmer Spectrum GX) and GC-MS (Model: Shimadzu-GCMS QP2010 Plus). A capillary column BPX-5 (29.5 m × 0.25 mm id., 0.25 μm thick film thickness) was used. The initial temperature of 40°C was held for 5 min. The temperature was programmed at 40 to 300°C at 5°C/min and followed by isothermal conditions for 30 min. The split ratio was 20 : 1 and the injection temperature was at 300°C. The injection size was 1 μL and the flow rate of carrier gas (Helium) was 1.5 mL/min. The ion source and transfer line temperatures were 290°C correspondingly. Data were collected in the full-scan mode from 28 to 500 with a solvent delay of 2 min. The compounds were determined by comparison with the mass spectra available in the NIST library in MS database.
3. Results and Discussion
3.1. Esterification of Bio-Oil
The chemical compositions of the PKO (Figure 1) and the EO at several parameters EO1, EO2, EO3, EO4, EO5, and EO6 (Figures 2(a)–2(f)) were characterized using GC-MS. In comparison to Figure 1, significant peaks at retention time, = 30.2, 34.7, 38.7, 41.9, and 42.3 min, were observed in the EO, which did not appear in PKO. These peaks were attributed to the formation of lauric acid ethyl ester, myristic acid ethyl ester, palmitic acid ethyl ester, oleic acid ethyl ester, and stearic acid ethyl ester, respectively [15]. The peak at = 12.9 min which represents phenol was observed to remain in the EO. The peaks of carboxylic acid such as lauric acid and myristic acid at = 29.5 and 34.0 min were not observed in the EO, indicating the conversion of carboxylic acids into ester. The peaks at = 17.1 and 28.3 min in PKO which represent pentanal and levoglucosan, respectively, were not observed in the EO. Meanwhile, other aldehyde and ketone groups in PKO remained in the EO at low proportions.
(a) EO1
(b) EO2
(c) EO3
(d) EO4
(e) EO5
(f) EO6
The percentage area (%) of EO was analysed for the relative contents of the compounds present in the EO at the same concentration. The main components of compounds present in the EO at different parameters and the comparison between EO concentrated at 35°C and 78°C are shown in Table 2. The total percentage area (%) of the desirable ester compounds was higher in the EO than in the PKO, which indicated the successful esterification of PKO. Doshi et al. [15] reported on the esterification of low molecular fatty acid (acetic acid and propanoic acid) and high molecular fatty acid in sewage sludge bio-oil. In comparison to Doshi et al. [15] study, it was observed that high molecular fatty acid of this bio-oil has been converted to its corresponding ester such as lauric acid ethyl ester, myristic acid ethyl ester, palmitic acid ethyl ester, and oleic acid ethyl ester. The low molecular fatty acid in esterification was not observed possibly due to a small fraction of the volatile acid in the bio-oil. This indicated that the ester compounds observed after the esterification were dependent on the organic acid in the bio-oil [16].
The undesirable compounds that are mainly responsible for the ageing reactions, instability, and corrosiveness such as aldehyde, ketones, and carboxylic acid were reduced in the EO. The anhydrosugar compound such as levoglucosan was also not observed in the EO. This is attributed from the extraction of EO using diethyl ether to separate the water soluble components in the EO [17]. Meanwhile, the phenol and phenolic compounds remained in the EO which displays inactive reactivity during catalytic esterification [18].
Increasing the ratio of ethanol to oil at 3 : 1 gave a decreasing trend of percentage area (%) of ester. The decreasing trend of percentage area (%) of ester might be due to water, a by-product obtained during esterification. Water is a major interference to acid catalyst esterification which obstructs the conversion of acids into ester to be completed [15, 18]. Water could inhibit the catalytic activity through deactivation of the sulphuric acid catalyst by the loss in acid durability of catalytic protons [19]. The use of molecular sieve 4A did not efficiently absorb water during esterification.
The unreacted ethanol was usually found in EO unless complete esterification has been achieved [15]. Therefore, EO was concentrated at 78°C using rotary evaporator in order to remove the unreacted ethanol and to investigate the difference in composition of EO as well as its properties. The EO which was concentrated at 78°C gave relatively similar composition with EO that was being concentrated at 35°C with relatively small changes in the percentage area (%) of some compounds.
The IR spectra of the PKO and the EO are shown in Figure 3. The IR spectra of EO (Figures 3(b) and 3(c)) showed similar properties of functional groups as compared to PKO (Figure 3(a)). The O–H stretching was observed at 3411 cm−1. The peak of C=O was observed at 1711 cm−1 and that of C–O at 1115 cm−1 which indicated the presence of ester. It was envisaged that the EO contains heavy oil as the IR showed similarity of functional groups present in PKO and EO. This is because esterification via reactive distillation could produce two types of modified bio-oil, which are light and heavy oil. The IR spectra of the light oil consisted of various ester compounds while the heavy oil was similar with the original bio-oil [14]. It was believed that the EO obtained in this study might consist of a mixture of light oil (volatile component) and heavy oil (nonvolatile component). No separation was performed on the volatile and nonvolatile component during esterification, which therefore resulted in similar IR spectra of PKO and EO.
(a)
(b)
(c)
3.2. Physical Characteristics of Esterified Bio-Oil (EO)
Physical characteristics of EO are summarised in Table 3. EO4 was characterized for the physical properties due to no carboxylic acid observed and less amount of ketones and aldehyde attributed to less oxygenated compound in the esterified oil. All EO gave a pleasant smell after esterification as compared to acrid smoky odour in PKO. The pleasant smell was due to the ethyl esters compounds which generally have a fruity essence [15].
The pH value of EO was assuaged from 3.37 to 5.09 and 5.12, which represent the conversion of carboxylic acids into neutral ester. This result was in agreement with the pH value of heavy oil reported in [14]. The pH value of EO was slightly lower than the commercial diesel. The density of EO was reduced from 1.07 g/cm3 to 0.94 g/cm3 and 0.95 g/cm3 which are comparable to other reported studies on catalytic esterification [14, 16].
The calorific value of EO was increased to 27% to perform heating value of 34.78 MJ/kg. The EO which was concentrated at 78°C gave a higher calorific value up to 41.52 MJ/kg. This result might be attributed from the elimination of unreacted ethanol in the EO. The incorporation with ethanol could reduce the extent of carbon in the mixture thus lowering the heating value of EO concentrated at 35°C as compared to EO concentrated at 78°C [15]. Esterification and dehydration of EO using molecular sieve assisted in decreasing the water content of bio-oil [16], thus resulting in higher calorific value of EO compared to PKO. The lower calorific value of EO compared to commercial diesel might be due to the existence of oxygenated compounds in the EO. The result is in agreement with the GC-MS analysis where high percentage of phenol and its derivatives was observed in the EO. In this study, the conversion of carboxylic into ester has primarily improved the pH of the bio-oil. Low pH of bio-oil indicates it is less corrosive when applied in the internal combustion engine [20]. Besides lowered acidity, the addition of polar solvents in the esterification like ethanol gives an immediate effect by lowering the density and increasing the calorific value of the bio-oil [21]. Thus, the esterified bio-oil could possibly be used in the more robust combustion engines, such as slow and medium-speed diesel engines, which require lower acidity and water content than those found in the raw bio-oil [20]. However, there are more specifications tests needed before the EO can be deemed suitable for real engine applications.
4. Conclusion
Esterification of PKO was performed with ethanol and sulphuric acid (as catalyst) to improve the pH and calorific value of the microwave bio-oil. The analysis of composition proved that the desirable ester compounds were found higher in the EO compared to pyrolytic oil before esterification, indicating the successful esterification of PKO. The undesirable compounds such as aldehyde, ketones, and carboxylic acid were reduced in the EO. The esterification procedure has improved the smell of the oil to an acceptable smell. The pH value of PKO was raised from 3.37 to 5.09 and 5.12 while the density of PKO was reduced from 1.07 to 0.94 and 0.95 g/cm3. Esterification has also improved the calorific value of the PKO from 27.19 to 34.78 and 41.52 MJ/kg. Conclusively, the EO has comparatively better properties in terms of its smell, pH, calorific value, and absence of environmentally undesirable compounds. However, future works should include ASTM 6751 specifications tests for biodiesel to evaluate the bio-oil’s suitability for commercial use.
Conflicts of Interest
The authors declare that they have no conflicts of interest.
Acknowledgments
The authors wish to express their appreciation to the Ministry of Higher Education Malaysia and Universiti Malaysia Sarawak for the financial support (Grant no. PRGS/TK04(01)/1268/2015(02)).