Research Article

The Effect of Menisci on Kinetic Analysis of Evaporation for Molten Alkali Metal Salts (CsNO3, CsCl, LiCl, and NaCl) in Small Cylindrical Containers

Table 1

Measured evaporation rates and experimental conditions used in isothermal thermogravimetric experiments for the molten alkali metal salts.

Molten saltTemperatureEvaporation rateAtmospheric Contact angle [37]Diameter of container
(°C)(mol/min)Gas(°)(cm)

CsCl8501.39 × 10−5Air312.1
8902.45 × 10−5
9304.28 × 10−5
9707.22 × 10−5
10001.78 × 10−4

CsNO35003.29 × 10−5Air222.1
5406.27 × 10−5
5801.12 × 10−4
6201.90 × 10−4
6603.08 × 10−4

LiCl [1, 22]8509.68 × 10−5Ar1363.0
9004.19 × 10−4
9504.19 × 10−50.4

NaCl [23] 9352.00 × 10−4Ar1133.81
9502.77 × 10−4
9854.03 × 10−4