Research Article
Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide
Table 2
Bond lengths and angles for NiL2 and CuL2 complexes.
| Atom | Atom | Bond lengths, Å | | Atom | Atom | Atom | Bond angles, ° |
| NiL2 | Ni(1) | O(2) | 1.848(3) | | O(2) | Ni(1) | O(1) | 85.05(12) | Ni(1) | O(1) | 1.849(3) | | O(2) | Ni(1) | S(2) | 94.91(9) | Ni(1) | S(2) | 2.1241(15) | | O(1) | Ni(1) | S(2) | 174.84(9) | Ni(1) | S(1) | 2.1254(16) | | O(2) | Ni(1) | S(1) | 174.78(8) | S(2) | C(11) | 1.716(4) | | O(1) | Ni(1) | S(1) | 95.26(9) | N(3) | C(14) | 1.305(4) | | S(2) | Ni(1) | S(1) | 85.26(6) | N(3) | C(11) | 1.324(4) | | C(4) | O(1) | Ni(1) | 131.4(2) | O(2) | C(14) | 1.264(4) | | C(14) | O(2) | Ni(1) | 131.2(2) | N(4) | C(11) | 1.329(4) | | C(11) | N(4) | C(12) | 123.4(3) | N(4) | C(12) | 1.445(5) | | C(11) | N(4) | C(13) | 120.0(3) | N(4) | C(13) | 1.458(5) | | C(12) | N(4) | C(13) | 116.6(3) | C(14) | C(15) | 1.480(5) | | N(3) | C(11) | N(4) | 115.1(3) | C(15) | C(16) | 1.378(5) | | N(4) | C(11) | S(2) | 117.0(3) | C(15) | C(20) | 1.383(5) | | C(1) | S(1) | Ni(1) | 107.56(13) | F(1) | C(18) | 1.345(4) | | C(11) | S(2) | Ni(1) | 107.29(13) |
| CuL2 | Cu(1) | O(1) | 1.9232(13) | | O(1) | Cu(1) | O(2) | 85.97(6) | Cu(1) | O(2) | 1.9293(14) | | O(1) | Cu(1) | S(2) | 169.33(5) | Cu(1) | S(2) | 2.2349(5) | | O(2) | Cu(1) | S(2) | 93.81(4) | Cu(1) | S(1) | 2.2384(6) | | O(1) | Cu(1) | S(1) | 93.37(4) | S(1) | C(1) | 1.7360(18) | | O(2) | Cu(1) | S(1) | 170.37(5) | F(1) | C(8) | 1.363(2) | | S(2) | Cu(1) | S(1) | 88.62(2) | O(1) | C(4) | 1.269(2) | | C(4) | O(1) | Cu(1) | 131.65(12) | N(1) | C(1) | 1.336(2) | | C(1) | N(1) | C(2) | 123.31(16) | N(1) | C(2) | 1.459(2) | | C(1) | N(1) | C(3) | 120.18(16) | N(1) | C(3) | 1.470(2) | | C(2) | N(1) | C(3) | 116.51(16) | N(2) | C(4) | 1.318(2) | | C(4) | N(2) | C(1) | 125.43(16) | N(2) | C(1) | 1.343(2) | | N(1) | C(1) | N(2) | 114.81(16) | C(4) | C(5) | 1.498(2) | | N(1) | C(1) | S(1) | 117.42(14) | C(5) | C (10) | 1.392(3) | | N(2) | C(1) | S(1) | 127.71(14) | C(5) | C(6) | 1.393(3) | | O(1) | C(4) | N(2) | 130.40(17) |
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