Research Article

Arsenic Mobility in As-Containing Soils from Geogenic Origin: Fractionation and Leachability

Table 1

Soil pH, pseudo-total Fe, Mn, and As content, and As fractionation in soil samples following the SEP procedure described by Lombi et al. (1999).

Sample pH 
(%)

(mg kg−1)

(mg kg−1)
F1 
(mg kg−1)
F2 
(mg kg−1)
F3 
(mg kg−1)
F4 
(mg kg−1)
F5 
(mg kg−1)
F6 
(mg kg−1)

16.42.23134890.13 (0.04%)12.19 (3.70%)20.87 (6.33%)86.28 (26.18%)123.37 (37.43%)86.71 (26.31%)
26.63.54013870.16 (0.05%)13.74 (3.95%)10.44 (3.00%)75.50 (21.72%)184.79 (53.17%)62.91 (18.10%)
37.14.65331940.08 (0.04%)5.86 (3.49%)5.70 (3.39%)28.70 (17.08%)102.01 (60.71%)25.69 (15.29%)
46.84.55312130.07 (0.05%)6.21 (3.94%)5.42 (3.44%)29.33 (18.60%)92.83 (58.87%)23.82 (15.11%)
56.33.03723590.09 (0.03%)8.82 (2.61%)9.33 (2.76%)56.89 (16.82%)168.76 (49.89%)94.35 (27.89%)
66.23.23244130.08 (0.02%)9.32 (2.44%)8.43 (2.21%)71.52 (18.76%)201.13 (52.75%)90.83 (23.82%)
76.02.93294250.08 (0.02%)9.53 (2.42%)9.61 (2.44%)77.11 (19.60%)225.82 (57.39%)71.31 (18.12%)
85.61.32001690.06 (0.05%)7.21 (5.72%)8.12 (6.43%)50.21 (39.78%)57.98 (45.94%)2.68 (2.13%)
96.96.729811080.01 (0.01%)3.18 (3.46%)2.66 (2.89%)14.56 (15.83%)43.35 (47.15%)28.21 (30.68%)

Figures in parentheses in the fractionation analysis indicate percentage of pseudo-total As solubilised in each step.