Research Article
Multicomponent Reactions, Solvent-Free Synthesis of 2-Amino-4-aryl-6-substituted Pyridine-3,5-dicarbonitrile Derivatives, and Corrosion Inhibitors Evaluation
Table 2
Corrosion rate, surface covering, and corrosion inhibition efficiency of 1, 5, 6, and 8 inhibitors at room temperature.
| No. | Dose (ppm) | 1 day | 3 days | 5 days | 7 days | 9 days | K (mg·cm−2h−1) | θ | η (%) | K (mg·cm−2h−1) | θ | η (%) | K (mg·cm−2h−1) | (θ) | η (%) | K (mg·cm−2h−1) | θ | η (%) | K (mg·cm−2h−1) | θ | η (%) |
| | Blank | 0.001590 | — | — | 0.001404 | — | — | 0.001484 | — | — | 0.00171 | — | — | 0.001968 | — | — | 1 | 200 | 0.001267 | 0.203 | 20.3 | 0.001029 | 0.2665 | 26.65 | 0.001046 | 0.2949 | 29.49 | 0.00116 | 0.3168 | 31.68 | 0.001202 | 0.3891 | 38.91 | 400 | 0.001059 | 0.3337 | 33.37 | 0.000876 | 0.3755 | 37.55 | 0.000886 | 0.4027 | 40.27 | 0.000911 | 0.4673 | 46.73 | 0.000922 | 0.5316 | 53.16 | 800 | 0.00090 | 0.4321 | 43.21 | 0.000750 | 0.4657 | 46.57 | 0.000732 | 0.5068 | 50.68 | 0.000705 | 0.5874 | 58.74 | 0.000704 | 0.6421 | 64.21 |
| 5 | 200 | 0.001057 | 0.3350 | 33.50 | 0.000832 | 0.4072 | 40.72 | 0.000842 | 0.4327 | 43.27 | 0.000873 | 0.4892 | 48.92 | 0.000850 | 0.5678 | 56.78 | 400 | 0.001010 | 0.3642 | 36.42 | 0.000794 | 0.4341 | 43.41 | 0.000795 | 0.4642 | 46.42 | 0.000839 | 0.5089 | 50.89 | 0.000806 | 0.5902 | 59.02 | 800 | 0.000832 | 0.4767 | 47.67 | 0.000617 | 0.5601 | 56.01 | 0.000607 | 0.5910 | 59.10 | 0.000582 | 0.6594 | 65.94 | 0.000569 | 0.7104 | 71.04 |
| 6 | 200 | 0.001148 | 0.2779 | 27.79 | 0.000983 | 0.2997 | 29.97 | 0.001000 | 0.3261 | 32.61 | 0.001100 | 0.3564 | 35.64 | 0.001097 | 0.4423 | 44.23 | 400 | 0.001021 | 0.3576 | 35.76 | 0.000801 | 0.429 | 42.9 | 0.000793 | 0.4654 | 46.54 | 0.000895 | 0.4762 | 47.62 | 0.000911 | 0.5369 | 53.69 | 800 | 0.000939 | 0.4092 | 40.92 | 0.000781 | 0.4432 | 44.32 | 0.000752 | 0.4929 | 49.29 | 0.000735 | 0.5697 | 56.97 | 0.000748 | 0.6199 | 61.99 |
| 8 | 200 | 0.001149 | 0.2772 | 27.72 | 0.000979 | 0.3021 | 30.21 | 0.001021 | 0.3120 | 31.20 | 0.001153 | 0.3254 | 32.54 | 0.001169 | 0.4060 | 40.60 | 400 | 0.00104 | 0.3415 | 34.15 | 0.000800 | 0.4296 | 42.96 | 0.000776 | 0.4771 | 47.71 | 0.000846 | 0.5048 | 50.48 | 0.000871 | 0.5573 | 55.73 | 800 | 0.000940 | 0.4083 | 40.83 | 0.000767 | 0.4532 | 45.32 | 0.000686 | 0.5374 | 53.74 | 0.000653 | 0.6181 | 61.81 | 0.000654 | 0.6675 | 66.74 |
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